Hydroperoxide, 1-phenylethyl, (R)-

Base Information

• Chemical Name: Hydroperoxide, 1-phenylethyl, (R)-
• CAS No.: 78833-98-4
• Molecular Formula: C8H10O2
• Molecular Weight: 138.166
• Mol file: 78833-98-4.mol

Synonyms:(R)-1-Phenyl-eth-1-yl-hydroperoxide;(R)-1-Phenyl-aethylhydroperoxid;(R)-1-phenyl-ethyl hydroperoxide;

Chemical Property of Hydroperoxide, 1-phenylethyl, (R)-

Chemical Property:

• Boiling Point: 66 °C (0.5 mmHg)
• PSA: 29.46000
• Density: 1.089±0.06 g/cm3(Predicted)
• LogP: 2.23720

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Hydroperoxide, 1-phenylethyl, (R)-

There total 13 articles about Hydroperoxide, 1-phenylethyl, (R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-phenylethyl hydroperoxide (3071-32-7) → (S)-1-phenylethanol (1445-91-6) + (R)-1-phenylethanol (1517-69-7) + (S)-(-)-(1-phenyl)ethylhydroperoxide (3071-32-7,78833-98-4,116181-13-6,116102-42-2)

Guidance literature:

With Brassica rapa var. rapa peroxidase; 2-methoxy-phenol; at 20 ℃; for 3.5h; pH=6; optical yield given as %ee; enantioselective reaction; aq. phosphate buffer; Enzymatic reaction;

DOI:10.1016/j.tetasy.2012.04.005

Reference yield:

1-phenylethyl hydroperoxide (3071-32-7) → (R)-1-phenylethanol (1517-69-7) + (S)-(-)-(1-phenyl)ethylhydroperoxide (3071-32-7,78833-98-4,116181-13-6,116102-42-2)

Guidance literature:

With 2-methoxy-phenol; In various solvent(s); at 20 ℃; Rate constant; Equilibrium constant; horseradish peroxydase, pH=6;

Reference yield:

1-phenylethyl hydroperoxide (3071-32-7) → (S)-1-phenylethanol (1445-91-6) + (R)-1-phenylethanol (1517-69-7) + (S)-(-)-(1-phenyl)ethylhydroperoxide (3071-32-7,78833-98-4,116181-13-6,116102-42-2) + (R)-(1-phenyl)ethyl hydroperoxide (78833-98-4)

Guidance literature:

With Aspergillus niger; Product distribution; biotransformation by diverse microorganisms, conversion percent, enantiomeric excess;

DOI:10.1021/jo9818327

upstream raw materials:

(R)-1-phenylethanol

1-phenylethyl hydroperoxide

1-Phenylethanol

(S)-1-phenylethanol

Downstream raw materials:

((S)-1-phenyl-ethyl)-xanthen-9-yl peroxide

(E)-3-phenylpropenal

2,3-epoxy-3-phenyl-1-propanol

benzaldehyde