(R)-(+)-α-phenethyl triphenylmethyl peroxide

Base Information

• Chemical Name: (R)-(+)-α-phenethyl triphenylmethyl peroxide
• CAS No.: 79144-42-6
• Molecular Formula: C₂₇H₂₄O₂
• Molecular Weight: 380.486
• Mol file: 79144-42-6.mol

Synonyms:(R)-(+)-α-phenethyl triphenylmethyl peroxide

Chemical Property of (R)-(+)-α-phenethyl triphenylmethyl peroxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (R)-(+)-α-phenethyl triphenylmethyl peroxide

There total 3 articles about (R)-(+)-α-phenethyl triphenylmethyl peroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

PtBr[O2CH(CH3)C6H5](P(C6H5)3)2*CH2Cl2 + bromo-triphenyl-methane (596-43-0) → cis-[PtBr2(PPh3)2] (26026-46-0,18517-48-1,16242-58-3) + (R)-(+)-α-phenethyl triphenylmethyl peroxide (79144-42-6)

Guidance literature:

In dichloromethane; byproducts: triphenylcarbinol; under N2 addn. at -40°C followed by stirring for 12 h at ambienttemp.; addn. of EtOH gave cis-PtBr2(PPh3)2, filtrate concd. under vac., from oil triphenylcarbinol obtained after addn. of hexane, hexane soln. concd., oil chromd., from upper layer of eluate obtained 1-phenylethyl triphenylmethyl peroxide;

DOI:10.1021/ja00409a035

Reference yield:

(S)-1-phenylethanol (1445-91-6) → (R)-(+)-α-phenethyl triphenylmethyl peroxide (79144-42-6)

Guidance literature:

Multi-step reaction with 2 steps

1: H₂SO₄; aqueous H₂O₂

With sulfuric acid; dihydrogen peroxide;

DOI:10.1039/jr9560000665

Reference yield:

triphenylmethyl alcohol (76-84-6) + (R)-(1-phenyl)ethyl hydroperoxide (78833-98-4) → (R)-(+)-α-phenethyl triphenylmethyl peroxide (79144-42-6)

Guidance literature:

DOI:10.1039/jr9580004637 DOI:10.1039/jr9560000665

upstream raw materials:

triphenylmethyl alcohol

(R)-(1-phenyl)ethyl hydroperoxide

(S)-1-phenylethanol

bromo-triphenyl-methane