2-(1-Iodo-2-phenylethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Base Information

Chemical Name:2-(1-Iodo-2-phenylethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
CAS No.:79121-47-4
Molecular Formula:C14H20BIO2
Molecular Weight:358.027
Hs Code.:
DSSTox Substance ID:DTXSID70524329
Nikkaji Number:J1.101.740A

Synonyms:79121-47-4;2-(1-Iodo-2-phenylethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;DTXSID70524329

Suppliers and Price of 2-(1-Iodo-2-phenylethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of 2-(1-Iodo-2-phenylethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:358.06011
Heavy Atom Count:18
Complexity:272

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B1(OC(C(O1)(C)C)(C)C)C(CC2=CC=CC=C2)I

Technology Process of 2-(1-Iodo-2-phenylethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

There total 2 articles about 2-(1-Iodo-2-phenylethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 66080-30-6
pinacol 2-phenyl-1-(phenylthio)ethane-1-boronate

: 7681-82-5,24359-64-6,41927-88-2,115813-40-6
sodium iodide

: 79121-47-4
pinacol 1-iodo-2-phenylethane-1-boronate

Guidance literature:: With methyl iodide; In N,N-dimethyl-formamide; byproducts: pinacol 2-phenylethene-1-boronate; under Ar or N2, mixt. kept in te dark at 20-25°C for 66 h; addn. of ether and pentane, mixt. washed with water, distd. elem. anal.;

Reference yield:

: pinacol 1-iodo-2-phenylethane-1-boronate ammonia complex

: 79121-47-4
pinacol 1-iodo-2-phenylethane-1-boronate

Guidance literature:: In chloroform-d1; byproducts: ammonia; dissolution in CDCl3; (1)H NMR data;
DOI:10.1021/om00082a019

Reference yield: 58.0%

: 124-42-5
acetamidine hydrochloride

: 79121-47-4
pinacol 1-iodo-2-phenylethane-1-boronate

: 88765-85-9
pinacol 1-acetamidino-2-phenylethane-1-boronate

Guidance literature:: With n-butyllithium; In tetrahydrofuran; diethyl ether; hexane; a suspn. of MeC(NH)NH2*HCl in THF was stirred at -78°C during the dropwise addn. of BuLi in hexane, mixt. warmed to 0°C, recooledto -78°C, boronate in ether was added, mixt. kept overnight at 20-25°C; concd. under vac., residue was treated with water and CH2Cl2, org. phase concd., residue recrystd. from ether-petroleum ether; elem. anal.;
DOI:10.1021/om00082a019