1-Aminoethylideneazanium;chloride

Base Information

• Chemical Name: 1-Aminoethylideneazanium;chloride
• CAS No.: 124-42-5
• Molecular Formula: C2H6N2^.HCl
• Molecular Weight: 94.544
• Hs Code.: 29252000
• Mol file: 124-42-5.mol

Synonyms:1-aminoethylideneazanium;chloride

Chemical Property of 1-Aminoethylideneazanium;chloride

Chemical Property:

• Appearance/Colour: white fine crystalline powder
• Vapor Pressure: 176mmHg at 25°C
• Melting Point: 165-170 °C(lit.)
• Refractive Index: 1.458
• Boiling Point: 62.8 °C at 760 mmHg
• PKA: pK1: 1.60(+1) (25°C)
• Flash Point: 26.1 °C
• PSA: 49.87000
• Density: 1.03g/cm³
• LogP: 1.54430
• Storage Temp.: Inert atmosphere,Room Temperature
• Sensitive.: Hygroscopic
• Water Solubility.: 1 g/mL
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 94.0297759
• Heavy Atom Count: 5
• Complexity: 25.5

Purity/Quality:

99% ^*data from raw suppliers

Acetamidine Hydrochloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38-36/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=[NH2+])N.[Cl-]
• Uses: Acetamidine Hydrochloride is a compound useful in organic synthesis. Acetamidine hydrochloride was used in the preparation of decarboxyectoine. It was also used in the synthesis of ethyl 4-(4-hydroxyphenyl)methylidene-2-methyl-5-oxo-1-imidazolacetate.

Technology Process of 1-Aminoethylideneazanium;chloride

There total 11 articles about 1-Aminoethylideneazanium;chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.5%

methyl acetimidate hydrochloride (14777-27-6) → acetamidine hydrochloride (124-42-5)

Guidance literature:

With ammonia; In methanol; at 0 - 28 ℃; for 2h; Temperature;

Reference yield:

acetamide (60-35-5) + hydrogenchloride (7647-01-0,15364-23-5) → N-acetylacetamide (625-77-4) + ammonium chloride + acetamidine hydrochloride (124-42-5) + acetic acid (64-19-7,77671-22-8)

Guidance literature:

beim Destillieren;

Reference yield:

N-hydroxyacetamidine monohydrochloride (5426-04-0) → acetamidine hydrochloride (124-42-5)

Guidance literature:

With ethanol; nickel; at 60 - 80 ℃; under 22065.2 Torr; Hydrogenation;

upstream raw materials:

N-hydroxyacetamidine monohydrochloride

acetonitrile

O-ethyl acetimidate

diethyl ether

Downstream raw materials:

4-Athyl-2,6-dimethylpyrimidin

5-amino-4-hexen-3-one

N,N,N'-tris-(4-nitro-benzenesulfenyl)-acetamidine

N-(2-methyl-6-oxo-1,6-dihydro-pyrimidin-5-yl)-benzamide

Refernces

• 1、 Hu, Wei-Xiao,Xu, Feng. "Synthesis, structures of some unsymmetrical 3,6-disubstituted-1,2,4,5- tetrazines". scheme or table. p. 1745 - 1750. Retrieved 2009/05/31.