Aziridine, 1-[(2,4-dinitrophenyl)thio]-2-methyl-3-phenyl-, cis-

Base Information

• Chemical Name: Aziridine, 1-[(2,4-dinitrophenyl)thio]-2-methyl-3-phenyl-, cis-
• CAS No.: 80056-40-2
• Molecular Formula: C₁₅H₁₃N₃O₄S
• Molecular Weight: 331.352
• Mol file: 80056-40-2.mol

Synonyms:

Chemical Property of Aziridine, 1-[(2,4-dinitrophenyl)thio]-2-methyl-3-phenyl-, cis-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Aziridine, 1-[(2,4-dinitrophenyl)thio]-2-methyl-3-phenyl-, cis-

There total 15 articles about Aziridine, 1-[(2,4-dinitrophenyl)thio]-2-methyl-3-phenyl-, cis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

S,S-diphenyl-N-(2,4-dinitrophenylsulfenyl)-N'-tosylsulfodiimide (924628-82-0) + 1-propenylbenzene (873-66-5) → trans-1-(2,4-dinitrophenylsulphenyl)-2-methyl-3-phenylaziridine (73155-20-1,80056-40-2)

Guidance literature:

In acetonitrile; at 80 ℃; for 1h;

DOI:10.1016/j.tetlet.2006.11.078

Reference yield: 97.0%

S,S-diphenyl-N-(2,4-dinitrophenylsulfenyl)-N'-tosylsulfodiimide (924628-82-0) + cis-1-phenyl-1-propylene (766-90-5) → cis-1-(2,4-dinitrophenylsulphenyl)-2-methyl-3-phenylaziridine (73155-20-1,80056-40-2)

Guidance literature:

In acetonitrile; at 80 ℃; for 1h;

DOI:10.1016/j.tetlet.2006.11.078

Reference yield: 64.0%

1-propenylbenzene (873-66-5) + 2,4-Dinitro-benzensulfensaeureamid (51824-83-0) → trans-1-(2,4-dinitrophenylsulphenyl)-2-methyl-3-phenylaziridine (73155-20-1,80056-40-2)

Guidance literature:

With lead(IV) acetate; In dichloromethane; for 0.5h; Ambient temperature;

DOI:10.1039/P19810002615

upstream raw materials:

2,4-Dinitro-benzensulfensaeureamid

cis-1-phenyl-1-propylene

2,4-dinitrobenzenesulphenamide of 1,4-dihydro-1,4-iminonaphthalene

1-propenylbenzene

Downstream raw materials:

N-(2-ethoxy-1-methyl-2-phenylethyl)-2,4-dinitrobenzenesulphenamide

trans-2-Phenyl-3-methylaziridine

Refernces

• 1、 Atkinson, Robert S.,Lee, Michael,Malpass, John R.. "An Efficient Thermal Route to Arenesulphenylnitrenes". . p. 919 - 920. Retrieved 2007/10/02.
• 2、 Atkinson, Robert S.,Judkins, Brian D.. "Intermolecular Trapping of Sulphenylnitrenes by Alkenes". . p. 2615 - 2619. Retrieved 2007/10/02.