Stannane, tributyl(3-ethenyl-2,4-dimethylphenyl)-

Base Information

Chemical Name:Stannane, tributyl(3-ethenyl-2,4-dimethylphenyl)-
CAS No.:820964-83-8
Molecular Formula:C22H38Sn
Molecular Weight:421.254
Hs Code.:
DSSTox Substance ID:DTXSID20458185

Synonyms:Stannane, tributyl(3-ethenyl-2,4-dimethylphenyl)-;820964-83-8;DTXSID20458185

Suppliers and Price of Stannane, tributyl(3-ethenyl-2,4-dimethylphenyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Stannane, tributyl(3-ethenyl-2,4-dimethylphenyl)-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:11
Exact Mass:422.199554
Heavy Atom Count:23
Complexity:300

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCC[Sn](CCCC)(CCCC)C1=C(C(=C(C=C1)C)C=C)C

Technology Process of Stannane, tributyl(3-ethenyl-2,4-dimethylphenyl)-

There total 1 articles about Stannane, tributyl(3-ethenyl-2,4-dimethylphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 646-05-9
pent-1-en-3-yne

: 56-35-9
bis(tri-n-butyltin)oxide

: 820964-83-8
2,6-dimethyl-3-(tributylstannyl)styrene

Guidance literature:: With maleic anhydride; N-cyclohexyl-1-[2-(diphenylphosphanyl)phenyl]methanimine; In tetrahydrofuran; 80°C, 24 h;
DOI:10.1021/ja044429s

Reference yield: 87.0%

: 4224-69-5
methyl 2-(bromomethyl)propenoate

: 820964-83-8
2,6-dimethyl-3-(tributylstannyl)styrene

: 820965-00-2
2-(2,4-dimethyl-3-vinyl-benzyl)-acrylic acid methyl ester

Guidance literature:: With tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; triphenylphosphine; In 1-methyl-pyrrolidin-2-one; at 100 ℃; for 3h;
DOI:10.1021/ja044429s

Reference yield:

: 820964-83-8
2,6-dimethyl-3-(tributylstannyl)styrene

: 820965-02-4
3-[3-(2-hydroxy-ethyl)-2,4-dimethyl-phenyl]-2,2-dimethyl-propionic acid methyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: 87 percent / Pd₂(dba)3; PPh₃ / 1-methyl-pyrrolidin-2-one / 3 h / 100 °C

2.1: CuI; MeLi; DIBAL-H / HMPA / tetrahydrofuran; diethyl ether; hexane / 1 h / -50 - -10 °C

2.2: 99 percent / tetrahydrofuran; diethyl ether; hexane / 25 h / -10 °C

3.1: Me₂CHCMe₂BH₂ / tetrahydrofuran / 3 h / 0 °C

3.2: 79 percent / NaOH; aq. H₂O₂ / tetrahydrofuran / 3 h / 20 °C

With copper(l) iodide; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; Thexylboran; methyllithium; diisobutylaluminium hydride; triphenylphosphine; N,N,N,N,N,N-hexamethylphosphoric triamide; In tetrahydrofuran; 1-methyl-pyrrolidin-2-one; diethyl ether; hexane;
DOI:10.1021/ja044429s