Benzene, [(5R)-5-(methoxymethoxy)-7-octenyl]-

Base Information

Chemical Name:Benzene, [(5R)-5-(methoxymethoxy)-7-octenyl]-
CAS No.:821785-91-5
Molecular Formula:C16H24O2
Molecular Weight:248.365
Hs Code.:
DSSTox Substance ID:DTXSID10473600

Synonyms:Benzene, [(5R)-5-(methoxymethoxy)-7-octenyl]-;821785-91-5;DTXSID10473600

Suppliers and Price of Benzene, [(5R)-5-(methoxymethoxy)-7-octenyl]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Benzene, [(5R)-5-(methoxymethoxy)-7-octenyl]-

Chemical Property:

XLogP3:4.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:10
Exact Mass:248.177630004
Heavy Atom Count:18
Complexity:197

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COCOC(CCCCC1=CC=CC=C1)CC=C
Isomeric SMILES:COCO[C@H](CCCCC1=CC=CC=C1)CC=C

Technology Process of Benzene, [(5R)-5-(methoxymethoxy)-7-octenyl]-

There total 2 articles about Benzene, [(5R)-5-(methoxymethoxy)-7-octenyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 107-30-2
chloromethyl methyl ether

: 821785-90-4
(R)-8-phenyloct-1-en-4-ol

: 821785-91-5
((R)-5-Methoxymethoxy-oct-7-enyl)-benzene

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In dichloromethane; at 0 ℃; for 3h;
DOI:10.1016/j.tetlet.2004.10.059

Reference yield:

: 36884-28-3
5-phenyl-1-pentanal

: 821785-91-5
((R)-5-Methoxymethoxy-oct-7-enyl)-benzene

Guidance literature:: Multi-step reaction with 2 steps

1: 82 percent / titanium S-BINOL complex / 12 h / 0 °C

2: 90 percent / DIPEA / CH₂Cl₂ / 3 h / 0 °C

With N-ethyl-N,N-diisopropylamine; titanium S-BINOL; In dichloromethane; 1: Maruoka asymmetric allylation;
DOI:10.1016/j.tetlet.2004.10.059

Reference yield:

: 821785-91-5
((R)-5-Methoxymethoxy-oct-7-enyl)-benzene

: 821785-95-9
(6S)-5,6-dihydro-6-[(2R)-2-(methoxymethoxy)-6-phenylhexyl]-2H-pyran-2-one

Guidance literature:: Multi-step reaction with 5 steps

1: OsO₄; NMO / acetone; H₂O / 4 h / 20 °C

2: NaIO₄ / 2 h / 20 °C

3: Ti(OiPr); S-BINOL / CH₂Cl₂ / 12 h / 20 °C

4: 85 percent / DIPEA / CH₂Cl₂ / 3 h / 20 °C

5: 80 percent / Grubb's catalyst / CH₂Cl₂ / 18 h / 20 °C

With titanium(IV) isopropylate; sodium periodate; osmium(VIII) oxide; N-methyl-2-indolinone; (S)-[1,1']-binaphthalenyl-2,2'-diol; N-ethyl-N,N-diisopropylamine; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane; water; acetone; 3: asymmetric Keck allylation;
DOI:10.1016/j.tetlet.2004.10.059