Morpholine, 4-(phenylseleno)-

Base Information

• Chemical Name: Morpholine, 4-(phenylseleno)-
• CAS No.: 82737-08-4
• Molecular Formula: C10H13NOSe
• Molecular Weight: 242.179
• DSSTox Substance ID: DTXSID80453934
• Wikidata: Q82275232
• Mol file: 82737-08-4.mol

Synonyms:Morpholine, 4-(phenylseleno)-;82737-08-4;4-phenyl selenomorpholine;DTXSID80453934

Chemical Property of Morpholine, 4-(phenylseleno)-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 243.01624
• Heavy Atom Count: 13
• Complexity: 142

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1COCCN1[Se]C2=CC=CC=C2

Technology Process of Morpholine, 4-(phenylseleno)-

There total 2 articles about Morpholine, 4-(phenylseleno)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

4-(trimethylsilyl)morpholine (13368-42-8) + Phenylselenyl chloride (5707-04-0) → N-(phenylselanyl)morpholine (82737-08-4)

Guidance literature:

In dichloromethane;

Reference yield: 77.0%

morpholine (110-91-8,99108-56-2) + Phenylselenyl bromide (34837-55-3) → N-(phenylselanyl)morpholine (82737-08-4)

Guidance literature:

In hexane; for 0.5h; Ambient temperature;

DOI:10.1002/mrc.1260251106

Reference yield: 97.0%

N-(phenylselanyl)morpholine (82737-08-4) + cyclohexene (110-83-8) → trans-1-bromo-2-phenylselanylcyclohexane

Guidance literature:

N-(phenylselanyl)morpholine; With phosphorus(V) oxybromide; In dichloromethane; at -30 ℃; for 0.0833333h;

cyclohexene; In dichloromethane; at -30 - 20 ℃;

DOI:10.1134/S1070428009060062

upstream raw materials:

morpholine

Phenylselenyl bromide

4-(trimethylsilyl)morpholine

Phenylselenyl chloride

Downstream raw materials:

morpholine

(Z)-3-phenyl-2-(phenylselenyl)acrylaldehyde

4-((E)-2-Phenylselanyl-but-1-enyl)-morpholine

(Z)-2-(phenylselanyl)but-2-enal

Refernces

• 1、 Back, Thomas G.,Kerr, Russell G.. "The metathesis of N-silylamines and benzeneselenenyl chloride. An efficient selenenamide synthesis". . p. 308 - 310. Retrieved 2007/10/02.