Silane, [2-[2,5-dimethoxy-4-[(1R)-1-phenyl-2-propenyl]phenoxy]ethyl]trimethyl-

Base Information

Chemical Name:Silane, [2-[2,5-dimethoxy-4-[(1R)-1-phenyl-2-propenyl]phenoxy]ethyl]trimethyl-
CAS No.:828933-83-1
Molecular Formula:C22H30O3Si
Molecular Weight:370.564
Hs Code.:

Synonyms:

Suppliers and Price of Silane, [2-[2,5-dimethoxy-4-[(1R)-1-phenyl-2-propenyl]phenoxy]ethyl]trimethyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Silane, [2-[2,5-dimethoxy-4-[(1R)-1-phenyl-2-propenyl]phenoxy]ethyl]trimethyl-

Chemical Property:

PSA：27.69000
LogP:5.73870

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Silane, [2-[2,5-dimethoxy-4-[(1R)-1-phenyl-2-propenyl]phenoxy]ethyl]trimethyl-

There total 10 articles about Silane, [2-[2,5-dimethoxy-4-[(1R)-1-phenyl-2-propenyl]phenoxy]ethyl]trimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 828933-82-0
{2-[2,5-Dimethoxy-4-((R)-1-phenyl-3-phenylselanyl-propyl)-phenoxy]-ethyl}-trimethyl-silane

: 828933-83-1
{2-[2,5-Dimethoxy-4-((R)-1-phenyl-allyl)-phenoxy]-ethyl}-trimethyl-silane

Guidance literature:: With sodium periodate; sodium hydrogencarbonate; In tetrahydrofuran; methanol; water; at 70 ℃; for 8h;
DOI:10.1021/jo048703c

Reference yield:

: 51061-83-7
2,4-dihydroxy-5-methoxybenzaldehyde

: 828933-83-1
{2-[2,5-Dimethoxy-4-((R)-1-phenyl-allyl)-phenoxy]-ethyl}-trimethyl-silane

Guidance literature:: Multi-step reaction with 8 steps

1: PPh₃; DIAD / tetrahydrofuran / 12 h / 20 °C

2: Hunig's base; DMAP / CH₂Cl₂

3: 83 percent / diethyl ether / 3 h / -78 - 20 °C

4: 91 percent / H₂O; CSA / acetonitrile; tetrahydrofuran / 6 h / 100 °C

5: 82 percent / LiAlH₄ / tetrahydrofuran / 0.08 h / 0 °C

6: 90 percent / diethyl ether / 12 h

7: 95 percent / PBu₃ / tetrahydrofuran / 5 h / 20 °C

8: 94 percent / NaIO₄; NaHCO₃ / H₂O; methanol; tetrahydrofuran / 8 h / 70 °C

With dmap; sodium periodate; lithium aluminium tetrahydride; tributylphosphine; di-isopropyl azodicarboxylate; camphor-10-sulfonic acid; water; sodium hydrogencarbonate; N-ethyl-N,N-diisopropylamine; triphenylphosphine; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; acetonitrile; 1: Mitsunobu reaction;
DOI:10.1021/jo048703c

Reference yield:

: 2916-68-9
2-(Trimethylsilyl)ethanol

: 828933-83-1
{2-[2,5-Dimethoxy-4-((R)-1-phenyl-allyl)-phenoxy]-ethyl}-trimethyl-silane

Guidance literature:: Multi-step reaction with 8 steps

1: PPh₃; DIAD / tetrahydrofuran / 12 h / 20 °C

2: Hunig's base; DMAP / CH₂Cl₂

3: 83 percent / diethyl ether / 3 h / -78 - 20 °C

4: 91 percent / H₂O; CSA / acetonitrile; tetrahydrofuran / 6 h / 100 °C

5: 82 percent / LiAlH₄ / tetrahydrofuran / 0.08 h / 0 °C

6: 90 percent / diethyl ether / 12 h

7: 95 percent / PBu₃ / tetrahydrofuran / 5 h / 20 °C

8: 94 percent / NaIO₄; NaHCO₃ / H₂O; methanol; tetrahydrofuran / 8 h / 70 °C

With dmap; sodium periodate; lithium aluminium tetrahydride; tributylphosphine; di-isopropyl azodicarboxylate; camphor-10-sulfonic acid; water; sodium hydrogencarbonate; N-ethyl-N,N-diisopropylamine; triphenylphosphine; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; acetonitrile; 1: Mitsunobu reaction;
DOI:10.1021/jo048703c