2-Propen-1-one, 1-phenyl-2-(trimethylsilyl)-

Base Information

• Chemical Name: 2-Propen-1-one, 1-phenyl-2-(trimethylsilyl)-
• CAS No.: 83845-70-9
• Molecular Formula: C12H16OSi
• Molecular Weight: 204.34000
• DSSTox Substance ID: DTXSID80446821
• Nikkaji Number: J2.686.300G
• Wikidata: Q82265544

Synonyms:2-Propen-1-one, 1-phenyl-2-(trimethylsilyl)-;83845-70-9;DTXSID80446821;alpha-(Trimethylsilyl)acrylophenone

Chemical Property of 2-Propen-1-one, 1-phenyl-2-(trimethylsilyl)-

Chemical Property:

• Boiling Point: 257.5±32.0 °C(Predicted)
• PSA: 17.07000
• Density: 0.938±0.06 g/cm3(Predicted)
• LogP: 3.30290
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 204.097041664
• Heavy Atom Count: 14
• Complexity: 231

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)C(=C)C(=O)C1=CC=CC=C1

Technology Process of 2-Propen-1-one, 1-phenyl-2-(trimethylsilyl)-

There total 2 articles about 2-Propen-1-one, 1-phenyl-2-(trimethylsilyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1-phenyl-2-(trimethylsilyl)-2-propen-1-ol (51666-96-7) → 2-trimethylsilyl-1-phenyl-2-propen-1-one (83845-70-9)

Guidance literature:

With Me₂Se*NCS; 1,8-diazabicyclo[5.4.0]undec-7-ene; In toluene; 1.)1h 0 deg C, 1h room temperature, 2.) 4h room temperature;

DOI:10.1021/jo00149a011

Reference yield:

1-phenyl-2-(trimethylsilyl)cyclopropene (102934-82-7) → 2-trimethylsilyl-1-phenyl-2-propen-1-one (83845-70-9) + 2-phenyl-1-trimethylsilylprop-2-en-1-one

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; at -40 ℃; for 0.166667h;

DOI:10.1016/S0040-4039(00)00566-9

Reference yield: 100.0%

2-trimethylsilyl-1-phenyl-2-propen-1-one (83845-70-9) + 2-methylphenyl aldehyde (529-20-4) → C20H24O2Si (1094063-87-2)

Guidance literature:

With tris(2,4,6-trimethoxyphenyl)phosphine; In propyl cyanide; Inert atmosphere;

DOI:10.1021/ol8026522

upstream raw materials:

1-phenyl-2-(trimethylsilyl)-2-propen-1-ol

1-phenyl-2-(trimethylsilyl)cyclopropene

Downstream raw materials:

(Z)-2-methyl-1-phenyl-2-(trimethylsilyl)vinyl diphenyl phosphate

2-[hydroxy(phenyl)methyl]-1-phenylprop-2-en-1-one

C₂₀H₂₄O₂Si

C₁₉H₂₁FO₂Si

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