51666-96-7Relevant articles and documents
Sila-morita-baylis-hillman reaction of Arylvinyl ketones: Overcoming the dimerization problem
Trofimov, Alexander,Gevorgyan, Vladimir
supporting information; experimental part, p. 253 - 255 (2009/06/28)
Arylvinyl ketones, under Morita-Baylis-Hillman (MBH) reaction conditions, produce a mixture of dimerization products. We propose a solution to this problem: a sila-MBH reaction. This cascade reaction involves addition of phosphine catalyst to arylvinyl ke
A regiodefined synthesis of α-trimethylsilyl ketones catalyzed by rhodium(I) hydride complex
Sato, Susumu,Matsuda, Isamu,Izumi, Yusuke
, p. 71 - 88 (2007/10/02)
Regiodefined synthesis of α-trimethylsilyl ketones is attained by one of three different routes: isomerization of β-trimethylsilyl allyl alcohols (route A), isomerization of β'-trimethylsilyl allyl alcohols (route B), and dehydrogenation of β-trimethylsil
A REGIOSPECIFIC SYNTHESIS OF TRIMETHYLSILYL ENOL ETHERS USING RHODIUM CATALYZED ISOMERIZATION OF β-TRIMETHYLSILYLALLYL ALCOHOLS
Matsuda, Isamu,Sato, Susumu,Izumi, Yusuke
, p. 2787 - 2790 (2007/10/02)
The rhodium catalyzed isomerization of β-trimethylsilylallyl alcohols has been successfully applied for the regiospecific synthesis of trimethylsilyl enol ethers.
