102934-82-7

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 102934-78-1 (Z)-1-iodo-2-phenyl-3-chloro-1-propene 
• 102934-73-6 (Z)-1-(trimethylsilyl)-1-iodo-2-phenyl-3-chloro-propene 
• 178425-56-4 1,1,2-tribromo-2-phenylcyclopropane 
• 5272-36-6 3-trimethylsilyl-2-propyn-1-ol 
• 70396-10-0 (Z)-3-iodo-2-phenyl-prop-2-en-1-ol 
• 102934-89-4 (Z)-3-(trimethylsilyl)-3-iodo-2-phenyl-2-propen-1-ol 
• 98-81-7 1-bromovinylbenzene 

Downstream Products

• 83845-70-9 2-trimethylsilyl-1-phenyl-2-propen-1-one 

Relevant academic research and scientific papers

Novel tetramerization of 1-trimethylsilyl-2-phenylcyclopropene

1-Trimethylsilyl-2-phenylcyclopropene (1) was generated from bromo- lithium exchange of 1-bromo-2-phenylcyclopropene followed by treatment with trimethylsilylchloride. Compound 1 underwent ene dimerizations to give endo and exo diners 5 and 6 which would dimerize by coupling reaction to yield a sole tetramer 4.

A MILD AND SELECTIVE SYNTHESIS OF CYCLOPROPENE AND CYCLOPROPANE DERIVATIVES VIA CYCLIALLYLATION OF ALKENYLLITHIUMS

Treatment of cis-1-iodo-3-chloro-1-propene derivatives, readily obtainable via trans addition of organometals to propargyl alcohols followed by iodinolysis and chlorination, with alkyllithiums, such as t-BuLi and n-BuLi, can proceed rapidly and cleanly ev