Technology Process of Tristannirane, hexakis(2,6-diethylphenyl)-
There total 2 articles about Tristannirane, hexakis(2,6-diethylphenyl)- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
lithium naphthalenide;
In
1,2-dimethoxyethane;
-78 °C, 15 min; room temp. 2 h; flash chromy., recrystn. from benzene;
DOI:10.1021/ja00341a058
- Guidance literature:
-
In
tetrahydrofuran;
addn. of soln. of aryllithium compd. to soln. of SnCl2 in THF, 0°C;
DOI:10.1021/ja00192a056
- Guidance literature:
-
With
Li; NH4Cl;
In
tetrahydrofuran;
addn. of freshly cut pieces of Li (1.17 mmol) to a partial suspension of (C6H3(C2H5)2)6Sn3 (0.87 mmol) in THF; stirring mixt. at room temp. for 18 h;; addn. of solid NH4Cl (6.54 mmol), stirring mixt. at room temp. for 1 h; filtering, concg. filtrate in vac.; taking up residue in min. vol. of 7:1 hexane/toluene; chromy. (silica gel column, elution with the same solvent mixt.); elem. anal.;;
DOI:10.1021/ja00044a011
