Technology Process of Pentastannabicyclo[1.1.1]pentane-1,3-diyl,
2,2,4,4,5,5-hexakis(2,6-diethylphenyl)-
There total 7 articles about Pentastannabicyclo[1.1.1]pentane-1,3-diyl,
2,2,4,4,5,5-hexakis(2,6-diethylphenyl)- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
toluene;
other Radiation; photolysis for 3.5h; soln. sealed in a Pyrex tube;
- Guidance literature:
-
With
Li; NH4Cl;
In
tetrahydrofuran;
addn. of freshly cut pieces of Li (5.22 mmol) to a suspension of (C6H3(C2H5)2)6Sn3 (0.87 mmol) in THF; stirring mixt. at room temp. for 18 h (react. is monitored by thin layer chromy.); removing excess Li by pipetting the THF soln. to a new flask;; addn. of solid NH4Cl, stirring mixt. at room temp. for 1 h; filtering, concg. filtrate in vac.; taking up residue in min. vol. of 7:1 hexane/toluene; chromy. (silica gel; hexane/toluene); elem. anal.; pptn. of C80H104Sn7 as toluene adduct;;
DOI:10.1021/ja00044a011
- Guidance literature:
-
With
Li;
In
tetrahydrofuran;
react. with excess Li in THF (18 h);;
DOI:10.1021/ja00044a011
