1-CYANO-4-METHYLNAPHTHALENE

Base Information

• Chemical Name: 1-CYANO-4-METHYLNAPHTHALENE
• CAS No.: 36062-93-8
• Molecular Formula: C12H9 N
• Molecular Weight: 167.21
• Hs Code.: 2926909090
• Mol file: 36062-93-8.mol

Synonyms:1-Cyano-4-methylnaphthalene;4-Cyano-1-methylnaphthalene; 4-Methyl-1-cyanonaphthalene;4-Methyl-1-naphthalenecarbonitrile; 4-Methyl-1-naphthonitrile

Chemical Property of 1-CYANO-4-METHYLNAPHTHALENE

Chemical Property:

• Melting Point: 52-56 °C(lit.)
• Boiling Point: 336.9°Cat760mmHg
• Flash Point: 158.3°C
• PSA: 23.79000
• Density: 1.11g/cm³
• LogP: 3.01988
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

98%Min ^*data from raw suppliers

4-Methylnaphthalene-1-carbonitrile ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn,Xi
• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-CYANO-4-METHYLNAPHTHALENE

There total 7 articles about 1-CYANO-4-METHYLNAPHTHALENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

methanol (67-56-1) + 4-Methoxy-benzoic acid 4-cyano-naphthalen-1-ylmethyl ester (145224-20-0) → 1-cyano-4-methylnaphthalene (36062-93-8) + 1-cyano-4-(methoxymethyl)naphthalene (112929-94-9) + 4-methoxybenzoic acid (100-09-4) + C24H16N2

Guidance literature:

Irradiation;

Reference yield: 100.0%

4-Methoxy-benzoic acid 4-cyano-naphthalen-1-ylmethyl ester (145224-20-0) → 1-cyano-4-methylnaphthalene (36062-93-8) + 1-cyano-4-(methoxymethyl)naphthalene (112929-94-9) + 4-methoxybenzoic acid (100-09-4) + C24H16N2

Guidance literature:

In methanol; Irradiation;

Reference yield: 55.0%

Benzoic acid 4-cyano-naphthalen-1-ylmethyl ester (145224-19-7) → 1-cyano-4-methylnaphthalene (36062-93-8) + 1-cyano-4-(methoxymethyl)naphthalene (112929-94-9) + C24H16N2 + benzoic acid (65-85-0,8013-63-6)

Guidance literature:

In methanol; Irradiation;

upstream raw materials:

methanol

Benzoic acid 4-cyano-naphthalen-1-ylmethyl ester

4-Methoxy-benzoic acid 4-cyano-naphthalen-1-ylmethyl ester

naphthalene-1,4-dicarbonitrile

Downstream raw materials:

4-Methyl-1-naphthoic acid

4-bromomethyl-1-naphthonitrile

1-n-butyl-4-methylnaphthalene

(E)-1-Ethyl-3-((4-(4,4,4-trifluoro-3-(3,4,5-trichlorophenyl)but-1-en-1-yl)naphthalen-1-yl)methyl)urea

Refernces

• 1、 Zhu, Yamin,Zhao, Mengdi,Lu, Wenkui,Li, Linyi,Shen, Zengming. "Acetonitrile as a cyanating reagent: Cu-catalyzed cyanation of arenes". supporting information. p. 2602 - 2605. Retrieved 2015/06/16.
• 2、 Lan, J. Y.,Schuster, Gary B.. "Photoalkylation of Dicyanoarenes with Alkyltriphenylborate Salts". . p. 6710 - 6711. Retrieved 2007/10/02.