[(2R,3S,4R)-4-acetyloxy-3-phenylmethoxy-3,4-dihydro-2H-pyran-2-yl]methyl acetate

Base Information

Chemical Name:[(2R,3S,4R)-4-acetyloxy-3-phenylmethoxy-3,4-dihydro-2H-pyran-2-yl]methyl acetate
CAS No.:65371-88-2
Molecular Formula:C17H20O6
Molecular Weight: 320.34
Hs Code.:
DSSTox Substance ID:DTXSID40370471
Wikidata:Q82157628

Synonyms:65371-88-2;4-O-benzyl-3,6-di-O-acetyl-D-glucal;[(2R,3S,4R)-4-acetyloxy-3-phenylmethoxy-3,4-dihydro-2H-pyran-2-yl]methyl acetate;SCHEMBL630040;DTXSID40370471;FTHQXTNSNIOZTL-ZACQAIPSSA-N

Suppliers and Price of [(2R,3S,4R)-4-acetyloxy-3-phenylmethoxy-3,4-dihydro-2H-pyran-2-yl]methyl acetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of [(2R,3S,4R)-4-acetyloxy-3-phenylmethoxy-3,4-dihydro-2H-pyran-2-yl]methyl acetate

Chemical Property:

Vapor Pressure:3.78E-07mmHg at 25°C
Boiling Point:416.6°Cat760mmHg
Flash Point:182°C
Density:1.2g/cm³
XLogP3:1.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:8
Exact Mass:320.12598835
Heavy Atom Count:23
Complexity:427

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:
Safety Statements: S24/25:Avoid contact with skin and eyes.;

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=O)OCC1C(C(C=CO1)OC(=O)C)OCC2=CC=CC=C2
Isomeric SMILES:CC(=O)OC[C@@H]1[C@H]([C@@H](C=CO1)OC(=O)C)OCC2=CC=CC=C2

Technology Process of [(2R,3S,4R)-4-acetyloxy-3-phenylmethoxy-3,4-dihydro-2H-pyran-2-yl]methyl acetate

There total 6 articles about [(2R,3S,4R)-4-acetyloxy-3-phenylmethoxy-3,4-dihydro-2H-pyran-2-yl]methyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 100-39-0
benzyl bromide

: 13265-84-4
D-glucal

: 65371-88-2,165524-90-3
3,6-Di-O-acetyl-4-O-benzyl-D-glucal

: 41898-01-5
4,6-Di-O-acetyl-3-O-benzyl-D-glucal

: 55628-54-1
3,4,6-tri-O-benzyl-D-glucal

: 165524-88-9
3-O-Acetyl-4,6-di-O-benzyl-D-glucal

Guidance literature:: With lithium bromide; In N,N-dimethyl-formamide; Yield given. Further byproducts given. Yields of byproduct given; Ambient temperature; electrolysis: Pt as working el., Ag/Ag(+) in CH₃CN as reference el.;

Reference yield:

: 108-24-7
acetic anhydride

: 100-39-0
benzyl bromide

: 13265-84-4
D-glucal

: 65371-88-2,165524-90-3
3,6-Di-O-acetyl-4-O-benzyl-D-glucal

: 41898-01-5
4,6-Di-O-acetyl-3-O-benzyl-D-glucal

: 55628-54-1
3,4,6-tri-O-benzyl-D-glucal

: 165524-88-9
3-O-Acetyl-4,6-di-O-benzyl-D-glucal

Guidance literature:: With pyridine; sodium bromide; Yield given. Multistep reaction. Yields of byproduct given; 1.) DMF, electrolysis: Pt as working el., Ag/Ag(+) in CH₃CN as reference el., room temp., 2.) room temp.;

Reference yield:

: 108-24-7
acetic anhydride

: 100-39-0
benzyl bromide

: 13265-84-4
D-glucal

: 65371-88-2,165524-90-3
3,6-Di-O-acetyl-4-O-benzyl-D-glucal

: 71110-96-8
3,4-Di-O-acetyl-6-O-benzyl-D-glucal

: 65371-87-1
6-O-acetyl-1,5-anhydro-3,4-di-O-benzyl-2-deoxy-D-arabino-hex-1-enitol

: 41898-01-5
4,6-Di-O-acetyl-3-O-benzyl-D-glucal

Guidance literature:: With pyridine; lithium hydride; Yield given. Multistep reaction. Further byproducts given. Yields of byproduct given; 1.) DMF, room temp., 2.) room temp.;