1-methoxy-2-[(Z)-2-nitroprop-1-enyl]benzene

Base Information

• Chemical Name: 1-methoxy-2-[(Z)-2-nitroprop-1-enyl]benzene
• CAS No.: 6306-34-9
• Molecular Formula: C10H11NO3
• Molecular Weight: 193.202
• Hs Code.: 2909309090
• NSC Number: 22984,14006
• Nikkaji Number: J1.102.050J
• ChEMBL ID: CHEMBL1986792
• Mol file: 6306-34-9.mol

Synonyms:1-methoxy-2-[(Z)-2-nitroprop-1-enyl]benzene;6306-34-9;Methyl 2-[(1Z)-2-nitro-1-propenyl]phenyl ether;(E)-1-Methoxy-2-(2-nitroprop-1-en-1-yl)benzene;NSC22984;SCHEMBL8129328;CHEMBL1986792;58645-50-4;NSC14006;NSC-14006;NSC-22984;1-Methoxy-2-(2-nitro-1-propenyl)benzene;1-methoxy-2-[(Z)-2-nitro-prop-1-enyl]-benzene;A834191;Q-103434

Chemical Property of 1-methoxy-2-[(Z)-2-nitroprop-1-enyl]benzene

Chemical Property:

• Vapor Pressure: 0.00142mmHg at 25°C
• Melting Point: 52-53℃
• Boiling Point: 306.1°C at 760 mmHg
• Flash Point: 136.9°C
• PSA: 55.05000
• Density: 1.156
• LogP: 2.85590
• XLogP3: 2.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 193.07389321
• Heavy Atom Count: 14
• Complexity: 232

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=CC1=CC=CC=C1OC)[N+](=O)[O-]
• Isomeric SMILES: C/C(=C/C1=CC=CC=C1OC)/[N+](=O)[O-]

Technology Process of 1-methoxy-2-[(Z)-2-nitroprop-1-enyl]benzene

There total 3 articles about 1-methoxy-2-[(Z)-2-nitroprop-1-enyl]benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

Nitroethane (79-24-3) + ortho-anisaldehyde (135-02-4) → 1-(2-methoxyphenyl)-2-nitropropene (6306-34-9)

Guidance literature:

With ammonium acetate; Reflux;

DOI:10.1002/poc.1631

Reference yield:

tetranitromethane (509-14-8) + 2-(1-propenyl)anisole (10577-44-3) → 1-(2-methoxyphenyl)-2-nitropropene (6306-34-9)

Guidance literature:

With pyridine; acetone;

Reference yield:

pyridine (110-86-1) + tetranitromethane (509-14-8) + 2-(1-propenyl)anisole (10577-44-3) + acetone (67-64-1) → 1-(2-methoxyphenyl)-2-nitropropene (6306-34-9)

Guidance literature:

upstream raw materials:

pyridine

tetranitromethane

2-(1-propenyl)anisole

acetone

Downstream raw materials:

3-(2-Methoxy-phenyl)-4-methyl-1H-pyrrole-2-carboxylic acid ethyl ester

ethyl 2,3-dioxobutyrate

4-(2-methoxyphenyl)-2,5-dimethyl-1H-pyrrole-3-carboxylic acid ethyl ester

5-<<1-(Ethoxycarbonyl)-2-oxopropyliden>amino>-4,5-dihydro-4-(2-methoxyphenyl)-2,5-dimethyl-3-furancarbonsaeure-ethylester