Benzaldehyde, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2-hydroxy-

Base Information

Chemical Name:Benzaldehyde, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2-hydroxy-
CAS No.:860613-37-2
Molecular Formula:C13H20O3Si
Molecular Weight:252.386
Hs Code.:
DSSTox Substance ID:DTXSID90460235
Nikkaji Number:J2.190.055I
Wikidata:Q82284223

Synonyms:860613-37-2;Benzaldehyde, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2-hydroxy-;SCHEMBL14697028;DTXSID90460235;5-((tert-Butyldimethylsilyl)oxy)-2-hydroxybenzaldehyde

Suppliers and Price of Benzaldehyde, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2-hydroxy-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Benzaldehyde, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2-hydroxy-

Chemical Property:

Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:252.11817103
Heavy Atom Count:17
Complexity:270

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)[Si](C)(C)OC1=CC(=C(C=C1)O)C=O

Technology Process of Benzaldehyde, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2-hydroxy-

There total 2 articles about Benzaldehyde, 5-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-2-hydroxy- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 1194-98-5
2,5-Dihydroxybenzaldehyde

: 18162-48-6
tert-butyldimethylsilyl chloride

: 860613-37-2
5-((tert-butyldimethylsilyl)oxy)-2-hydroxybenzaldehyde

Guidance literature:: 2,5-Dihydroxybenzaldehyde; With 1H-imidazole; In dichloromethane;

tert-butyldimethylsilyl chloride; In dichloromethane; at 20 ℃;

Reference yield: 61.0%

: 113984-70-6
2,5-bis(tert-butyldimethylsilyloxy)benzaldehyde

: 860613-37-2
5-((tert-butyldimethylsilyl)oxy)-2-hydroxybenzaldehyde

Guidance literature:: With zinc(II) chloride; In 1,2-dichloro-ethane; at 80 ℃;
DOI:10.1016/j.tetlet.2012.07.103

Reference yield: 100.0%

: 861216-48-0
tert-butyl 2-methylbut-3-en-2-yl carbonate

: 860613-37-2
5-((tert-butyldimethylsilyl)oxy)-2-hydroxybenzaldehyde

: 5-((tert-butyldimethylsilyl)oxy)-2-((2-methylbut-3-en-2-yl)oxy)benzaldehyde

Guidance literature:: tert-butyl 2-methylbut-3-en-2-yl carbonate; 5-((tert-butyldimethylsilyl)oxy)-2-hydroxybenzaldehyde; In tetrahydrofuran; at 0 ℃; Molecular sieve; Inert atmosphere;

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 4 ℃; for 12h; Inert atmosphere;
DOI:10.1002/ejoc.201501151