Benzene, 1,4-dibromo-2-(dimethoxymethyl)-

Base Information

Chemical Name:Benzene, 1,4-dibromo-2-(dimethoxymethyl)-
CAS No.:861928-15-6
Molecular Formula:C9H10Br2O2
Molecular Weight:309.98300
Hs Code.:
DSSTox Substance ID:DTXSID80479674
Nikkaji Number:J2.196.129I
Wikidata:Q82313818
Mol file:861928-15-6.mol

Synonyms:861928-15-6;Benzene, 1,4-dibromo-2-(dimethoxymethyl)-;DTXSID80479674

Suppliers and Price of Benzene, 1,4-dibromo-2-(dimethoxymethyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
1,4-DIBROMO-2-(DIMETHOXYMETHYL)BENZENE 95.00%
5MG
$ 495.88

Total 1 raw suppliers

Chemical Property of Benzene, 1,4-dibromo-2-(dimethoxymethyl)-

Chemical Property:

PSA：18.46000
LogP:3.50300
XLogP3:2.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:309.90271
Heavy Atom Count:13
Complexity:151

Purity/Quality:: 1,4-DIBROMO-2-(DIMETHOXYMETHYL)BENZENE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(C1=C(C=CC(=C1)Br)Br)OC

Technology Process of Benzene, 1,4-dibromo-2-(dimethoxymethyl)-

There total 1 articles about Benzene, 1,4-dibromo-2-(dimethoxymethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 74553-29-0
2,5-dibromobenzaldehyde

: 149-73-5
trimethyl orthoformate

: 861928-15-6
1,4-dibromo-2-(dimethoxymethyl)benzene

Guidance literature:: With sulfuric acid; In methanol; at 60 ℃; for 1h;
DOI:10.1016/j.tet.2005.04.051

Reference yield: 79.0%

: 861928-15-6
1,4-dibromo-2-(dimethoxymethyl)benzene

: 4-bromo-2-formylphenylboronic acid

Guidance literature:: 1,4-dibromo-2-(dimethoxymethyl)benzene; With n-butyllithium; In diethyl ether; at -78 ℃; for 0.25h;

With triethyl borate; In diethyl ether; at -78 - -50 ℃; for 0.5h; Further stages.;
DOI:10.1039/b611195e

Reference yield: 79.0%

: 861928-15-6
1,4-dibromo-2-(dimethoxymethyl)benzene

: 150-46-9
triethyl borate

: 4-bromo-2-formylphenylboronic acid

Guidance literature:: With n-butyl lithium; HCl; In diethyl ether; under Ar; soln. of 1,4-Br2-2-(MeO)2CH-C6H3 in Et2O added to nBuLi/Et2O at -78°C, stirred (15 min), B(OEt)3 added, mixt. stirred for 0.5 h, 2M HCl added at -50°C, org. phase sepd., evapn., dild. aq. HCl added, soln. heated at 70°C; evapn. under vac., solid filtered off, washed with water and toluene; elem. anal.;
DOI:10.1039/b611195e