tert-Butylhydrazine

Base Information

• Chemical Name: tert-Butylhydrazine
• CAS No.: 32064-67-8
• Molecular Formula: C4H12 N2
• Molecular Weight: 88.1527
• Hs Code.: 2928000090
• European Community (EC) Number: 664-395-7
• DSSTox Substance ID: DTXSID90185875
• Nikkaji Number: J43.136B
• Wikidata: Q83057022
• Mol file: 32064-67-8.mol

Synonyms:tert-butylhydrazine;tert-butylhydrazine monohydrochloride

Chemical Property of tert-Butylhydrazine

Chemical Property:

• Melting Point: 85 °C
• Boiling Point: 135°Cat760mmHg
• PKA: 8.92±0.70(Predicted)
• Flash Point: 35.8°C
• PSA: 38.05000
• Density: 0.823g/cm³
• LogP: 1.33940
• XLogP3: 0
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 88.100048391
• Heavy Atom Count: 6
• Complexity: 35.3

Purity/Quality:

98%,99%, ^*data from raw suppliers

tert-Butyl hydrazine 95 ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C)NN

Technology Process of tert-Butylhydrazine

There total 13 articles about tert-Butylhydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 11.0%

tertiary butyl chloride (507-20-0) → tert-butylhydrazine (32064-67-8)

Guidance literature:

With hydrazine hydrate; at 50 ℃; for 3h;

Reference yield:

tertbutylhydrazine hydrochloride (7400-27-3) → tert-butylhydrazine (32064-67-8)

Guidance literature:

With sodium carbonate; In acetonitrile; at 50 - 140 ℃;

Reference yield:

tert-butyl alcohol (75-65-0) → tert-butylhydrazine (32064-67-8)

Guidance literature:

With hydrazine hydrate; at 120 ℃; for 6h; Temperature; Inert atmosphere; Autoclave;

upstream raw materials:

tertiary butyl chloride

benzophenone-tert-butylhydrazone

tert-butylamine

diethyl ether

Downstream raw materials:

tert-butylamine

N-[1-(2-Bromo-phenyl)-eth-(Z)-ylidene]-N'-tert-butyl-hydrazine

2-<3-(1,1-Dimethylethyl)-4-oxo-3,4-dihydrophthalazin-1-ylmethyl>-benzoesaeure

1-t-butylhydrazone of 2-benzoyl-1,3-indandione

Refernces

• 1、 -. "The preparation method of the uncle butyl jing". Paragraph 0006; 0007; 0008-0010. . Retrieved 2018/07/30.
• 2、 -. "A method for the preparation of tertiary butyl jing (by machine translation)". Paragraph 0006; 0007; 0008; 0010. . Retrieved 2018/07/30.