(Z)-1-Phenyl-1-butene

Base Information

• Chemical Name: (Z)-1-Phenyl-1-butene
• CAS No.: 1560-09-4
• Molecular Formula: C10H12
• Molecular Weight: 132.205
• Hs Code.: 2902909090
• Nikkaji Number: J91.286G
• Mol file: 1560-09-4.mol

Synonyms:[(Z)-but-1-enyl]benzene;(Z)-1-Phenyl-1-butene;(Z)-1-butenylbenzene;1560-09-4;Benzene, 1-butenyl-, (Z)-;cis-8-ethylstyrene;1-phenyl-(Z)-1-butene;1-((Z)-But-1-enyl)benzene;1-Butene, 1-phenyl-, (Z)-;MPMBRWOOISTHJV-CLTKARDFSA-N

Chemical Property of (Z)-1-Phenyl-1-butene

Chemical Property:

• Melting Point: -41.43°C (estimate)
• Refractive Index: 1.5364
• Boiling Point: 189°Cat760mmHg
• Flash Point: 63.6°C
• PSA: 0.00000
• Density: 0.899g/cm³
• LogP: 3.10980
• XLogP3: 3.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 132.093900383
• Heavy Atom Count: 10
• Complexity: 96.6

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC=CC1=CC=CC=C1
• Isomeric SMILES: CC/C=C\C1=CC=CC=C1

Technology Process of (Z)-1-Phenyl-1-butene

There total 70 articles about (Z)-1-Phenyl-1-butene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

1-phenyl-1-butyne (622-76-4,83585-27-7) → (Z)-but-1-en-1-ylbenzene (1560-09-4)

Guidance literature:

With copper(II) bis(trifluoromethanesulfonate); dimethylamine borane; In water; at 40 ℃; for 2h; chemoselective reaction;

DOI:10.1039/c4ra11193a

Reference yield: 72.0%

n-propyltriphenylphosphonium bromide (6228-47-3) + benzaldehyde (100-52-7) → (Z)-but-1-en-1-ylbenzene (1560-09-4) + trans-1-phenyl-1-butene (1005-64-7) + Triphenylphosphine oxide (791-28-6)

Guidance literature:

With potassium carbonate; In methanol; at 65 ℃; for 1h; Yield given;

DOI:10.1016/S0040-4020(01)87536-0

Reference yield: 70.0%

1-phenyl-1-butyne (622-76-4,83585-27-7) → (Z)-but-1-en-1-ylbenzene (1560-09-4) + trans-1-phenyl-1-butene (1005-64-7) + 1-butylbenzene (104-51-8)

Guidance literature:

With hydrogen; In tetrahydrofuran; at 50 ℃; for 16h; under 3750.38 Torr; stereoselective reaction; Autoclave; Glovebox;

DOI:10.1039/c7cc01779k

upstream raw materials:

methyl bromide

1-phenylpropenyl-lithium

iodobenzene

di((Z)-1-butenyl)cuprate

Downstream raw materials:

1-phenyl-1-(trichlorosilyl)butane

(1S,2R)-1-phenylbutane-1,2-diol

(1R,2S)-1-phenylbutane-1,2-diol

2-ethyl-3-phenyloxirane