[2-(Dimethylsilyl)ethyl](diphenyl)phosphane

Base Information

• Chemical Name: [2-(Dimethylsilyl)ethyl](diphenyl)phosphane
• CAS No.: 86934-58-9
• Molecular Formula: C16H21PSi
• Molecular Weight: 272.402
• DSSTox Substance ID: DTXSID40833157

Synonyms:[2-(Dimethylsilyl)ethyl](diphenyl)phosphane;86934-58-9;SCHEMBL10385850;DTXSID40833157

Chemical Property of [2-(Dimethylsilyl)ethyl](diphenyl)phosphane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 5
• Exact Mass: 271.10718917
• Heavy Atom Count: 18
• Complexity: 199

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)CCP(C1=CC=CC=C1)C2=CC=CC=C2

Technology Process of [2-(Dimethylsilyl)ethyl](diphenyl)phosphane

There total 2 articles about [2-(Dimethylsilyl)ethyl](diphenyl)phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

[2-(dimethylchlorosilyl)ethyl]diphenylphosphane (72824-21-6) → 2-dimethylsilyl-1-diphenylphosphinoethane (86934-58-9)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; at 20 ℃; for 2h;

Reference yield:

diphenylphosphane (829-85-6) → 2-dimethylsilyl-1-diphenylphosphinoethane (86934-58-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 71 percent / 5 h / Irradiation

2: 83 percent / LiAlH₄ / diethyl ether / 2 h / 20 °C

With lithium aluminium tetrahydride; In diethyl ether;

Reference yield: 90.0%

bis(cycloocta-1,5-diene)platinum(0) (12130-66-4) + 2-dimethylsilyl-1-diphenylphosphinoethane (86934-58-9) → {Pt(P(C6H5)2CH2CH2Si(CH3)2)2} (80298-94-8)

Guidance literature:

In diethyl ether; 10 min, 25°C; characterized spect. and by microanal.;

DOI:10.1039/c39810000937

upstream raw materials:

[2-(dimethylchlorosilyl)ethyl]diphenylphosphane

diphenylphosphane

Downstream raw materials:

diphenyl(methyl)phosphine

{Pt(P(C₆H₅)2CH₂CH₂Si(CH₃)2)2}

{rac-(OC-6-45)-carbonylchlorohydrido{(2-(diphenylphosphino)ethyl)dimethylsilyl}(triphenylphosphine)iridium}

Ir(P(C₆H₅)2CH₂CH₂Si(CH₃)2)(P(C₆H₅)3)(H)2(CO)

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