{rac-(OC-6-45)-carbonylchlorohydrido{(2-(diphenylphosphino)ethyl)dimethylsilyl}(triphenylphosphine)iridium}

Base Information

Chemical Name:{rac-(OC-6-45)-carbonylchlorohydrido{(2-(diphenylphosphino)ethyl)dimethylsilyl}(triphenylphosphine)iridium}
CAS No.:88453-23-0
Molecular Formula:C₃₅H₃₆ClIrOP₂Si
Molecular Weight:790.376
Hs Code.:

Synonyms:{rac-(OC-6-45)-carbonylchlorohydrido{(2-(diphenylphosphino)ethyl)dimethylsilyl}(triphenylphosphine)iridium}

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Chemical Property of {rac-(OC-6-45)-carbonylchlorohydrido{(2-(diphenylphosphino)ethyl)dimethylsilyl}(triphenylphosphine)iridium}

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Technology Process of {rac-(OC-6-45)-carbonylchlorohydrido{(2-(diphenylphosphino)ethyl)dimethylsilyl}(triphenylphosphine)iridium}

There total 1 articles about {rac-(OC-6-45)-carbonylchlorohydrido{(2-(diphenylphosphino)ethyl)dimethylsilyl}(triphenylphosphine)iridium} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 15318-31-7,14871-41-1,59246-46-7
bis(triphenylphosphine)iridium(I) carbonyl chloride

: 86934-58-9
2-dimethylsilyl-1-diphenylphosphinoethane

: 88453-23-0
{rac-(OC-6-45)-carbonylchlorohydrido{(2-(diphenylphosphino)ethyl)dimethylsilyl}(triphenylphosphine)iridium}

Guidance literature:: In benzene; stirring for 10 min; evapn.; residue was dissolved in boiling hexane, then cooled, the supernatant was removed and discarded, recrystn. for four times from CH2Cl2/hexane, elem. anal.;
DOI:10.1021/ja00317a024

Reference yield: 60.0%

: 16853-85-3
lithium aluminium tetrahydride

: 88453-23-0
{rac-(OC-6-45)-carbonylchlorohydrido{(2-(diphenylphosphino)ethyl)dimethylsilyl}(triphenylphosphine)iridium}

: 88453-32-1
Ir(P(C₆H₅)2CH₂CH₂Si(CH₃)2)(P(C₆H₅)3)(H)2(CO)

Guidance literature:: In tetrahydrofuran; stirring overnight, refluxed for 8h; addn. of MeOH, removal of volatiles, redissolved in THF, filtered under N2 through a plug of alumina, pptd. from hexane, elem. anal.;
DOI:10.1021/ja00317a024

Reference yield:

: 88453-23-0
{rac-(OC-6-45)-carbonylchlorohydrido{(2-(diphenylphosphino)ethyl)dimethylsilyl}(triphenylphosphine)iridium}

: 7647-15-6
sodium bromide

: 88453-34-3
Ir(P(C₆H₅)2CH₂CH₂Si(CH₃)2)(P(C₆H₅)3)(H)(CO)(Br)

Guidance literature:: In acetone; excess NaBr, 15h; removing the solvent, dissolving in THF, washing down a short column packed with alumina, addn. of hexane, elem.anal.;
DOI:10.1021/ja00317a024