2-Ethylfuran

Base Information

• Chemical Name: 2-Ethylfuran
• CAS No.: 3208-16-0
• Molecular Formula: C6H8O
• Molecular Weight: 96.1289
• Hs Code.: 29321900
• European Community (EC) Number: 221-714-0
• UNII: T8O6J71T9O
• DSSTox Substance ID: DTXSID7062906
• Nikkaji Number: J45.568G
• Wikidata: Q17989420
• Metabolomics Workbench ID: 49097
• ChEMBL ID: CHEMBL2269084
• Mol file: 3208-16-0.mol

Synonyms:2-ethylfuran

Chemical Property of 2-Ethylfuran

Chemical Property:

• Appearance/Colour: clear colorless to yellow liquid
• Vapor Pressure: 53.9mmHg at 25°C
• Melting Point: -62.8°C (estimate)
• Refractive Index: n20/D 1.439(lit.)
• Boiling Point: 94.5 °C at 760 mmHg
• Flash Point: 28°F
• PSA: 13.14000
• Density: 0.915 g/cm³
• LogP: 1.84200
• Storage Temp.: 0-6°C
• Sensitive.: Air Sensitive
• XLogP3: 2.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 96.057514874
• Heavy Atom Count: 7
• Complexity: 52.1

Purity/Quality:

99.9% ^*data from raw suppliers

2-Ethylfuran ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F， Xi
• Hazard Codes: F,Xi
• Statements: 11
• Safety Statements: 16-29-33-9

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCC1=CC=CO1
• Uses: 2-Ethylfuran was used to investigate the gas phase products formed from the Cl atoms initiated reactions of 2-ethylfuran by in situ long-path FTIR absorption spectroscopy. It was also used in the synthesis of 4-oxo-(E)-2-hexenal via ring opening reaction using aqueous N-bromosuccinimide.

Technology Process of 2-Ethylfuran

There total 26 articles about 2-Ethylfuran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

(Z)-hex-2-ene-1,4-diol (83726-18-5) → 2-ethylfuran (3208-16-0)

Guidance literature:

With oxygen; palladium diacetate; copper (I) acetate; at 100 ℃; for 9h;

Reference yield: 42.0%

trans-4-hydroxy-2-hexenal (17427-08-6,150408-28-9,150408-31-4,17427-21-3,160708-91-8) → 2-ethylfuran (3208-16-0)

Guidance literature:

at 100 - 150 ℃;

DOI:10.1134/S1070428010030188

Reference yield:

furan (110-00-9) + ethanol (64-17-5) → 2-ethylfuran (3208-16-0) + 1-benzofurane (271-89-6) + ethylbenzene (100-41-4,27536-89-6)

Guidance literature:

With zeolite HUSY (Si/Al = 250); at 300 ℃; for 8h; Reagent/catalyst; Catalytic behavior; Activation energy;

DOI:10.1021/acscatal.7b03952

upstream raw materials:

furan

ethene

(furan-2-yl)ethylene

1-(2-furyl)-1-ethanone

Downstream raw materials:

5-ethylfurfural

2-acetyl-5-ethylfuran

2-ethyltetrahydrofuran

n-hexan-3-one

Refernces

• 1、 Teixeira, Ivo F.,Lo, Benedict T. W.,Kostetskyy, Pavlo,Ye, Lin,Tang, Chiu C.,Mpourmpakis, Giannis,Tsang, Shik Chi Edman. "Direct Catalytic Conversion of Biomass-Derived Furan and Ethanol to Ethylbenzene". . p. 1843 - 1850. Retrieved 2018/03/09.
• 2、 Kim, Beom-Sik,Jeong, Chang Seok,Kim, Ji Man,Park, Su Bin,Park, Sung Hoon,Jeon, Jong-Ki,Jung, Sang-Chul,Kim, Sang Chai,Park, Young-Kwon. "Ex situ catalytic upgrading of lignocellulosic biomass components over vanadium contained H-MCM-41 catalysts". . p. 184 - 191. Retrieved 2016/03/08.