1-Phenyl-2,5,8,11,14-pentaoxapentadecane

Base Information

• Chemical Name: 1-Phenyl-2,5,8,11,14-pentaoxapentadecane
• CAS No.: 87117-61-1
• Molecular Formula: C16H26O5
• Molecular Weight: 298.379
• DSSTox Substance ID: DTXSID60511602
• Wikidata: Q82370476
• Mol file: 87117-61-1.mol

Synonyms:87117-61-1;1-PHENYL-2,5,8,11,14-PENTAOXAPENTADECANE;SCHEMBL10709681;DTXSID60511602

Chemical Property of 1-Phenyl-2,5,8,11,14-pentaoxapentadecane

Chemical Property:

• XLogP3: 1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 14
• Exact Mass: 298.17802393
• Heavy Atom Count: 21
• Complexity: 207

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COCCOCCOCCOCCOCC1=CC=CC=C1

Technology Process of 1-Phenyl-2,5,8,11,14-pentaoxapentadecane

There total 8 articles about 1-Phenyl-2,5,8,11,14-pentaoxapentadecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

1-phenyl-2,5,8,11-tetraoxatridecan-13-ol (86259-87-2,1201808-31-2) + methyl iodide (74-88-4) → 1-phenyl-2,5,8,11,14-pentaoxapentadecane (87117-61-1)

Guidance literature:

With sodium; In toluene; at 60 ℃;

DOI:10.1002/hlca.19840670813

Reference yield:

2-(Benzyloxy)ethyl p-toluenesulfonate (4981-83-3) + triethylene glycol di-(p-toluenesulfonate) (19249-03-7) → 1-phenyl-2,5,8,11,14-pentaoxapentadecane (87117-61-1)

Guidance literature:

With sodium hydride; Yield given. Multistep reaction; 1) 30 min, r. t., THF, 2) 6 h, reflux, THF;

Reference yield:

Tetraethylene glycol (112-60-7) → 1-phenyl-2,5,8,11,14-pentaoxapentadecane (87117-61-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 50 percent / Na / 3 h / 100 °C

2: 80 percent / Na / toluene / 60 °C

With sodium; In toluene;

DOI:10.1002/hlca.19840670813

upstream raw materials:

2-(Benzyloxy)ethyl p-toluenesulfonate

triethylene glycol di-(p-toluenesulfonate)

1-phenyl-2,5,8,11-tetraoxatridecan-13-ol

dimethyl sulfate

Downstream raw materials:

tetraethylene glycol monomethyl ether

4,7,10,13,16-pentaoxa-1-heptadecene

2,5,8,11-tetraoxatridecan-13-ol tosylate