Dodecyl carbamate

Base Information

• Chemical Name: Dodecyl carbamate
• CAS No.: 6320-52-1
• Molecular Formula: C13H27NO2
• Molecular Weight: 229.359
• Hs Code.: 2924199090
• NSC Number: 31209
• DSSTox Substance ID: DTXSID20283398
• Nikkaji Number: J2.090.554I
• Wikidata: Q82017951
• Mol file: 6320-52-1.mol

Synonyms:dodecyl carbamate;6320-52-1;n-dodecyl carbamate;NSC31209;Carbamic acid lauryl ester;SCHEMBL43998;DTXSID20283398;NSC 31209;NSC-31209

Chemical Property of Dodecyl carbamate

Chemical Property:

• Vapor Pressure: 0.000134mmHg at 25°C
• Melting Point: 81-82 °C
• Boiling Point: 333.7°Cat760mmHg
• PKA: 13.52±0.50(Predicted)
• Flash Point: 105.7°C
• PSA: 52.32000
• Density: 0.916g/cm³
• LogP: 4.70290
• XLogP3: 5
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 12
• Exact Mass: 229.204179104
• Heavy Atom Count: 16
• Complexity: 160

Purity/Quality:

99% min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCCOC(=O)N

Technology Process of Dodecyl carbamate

There total 6 articles about Dodecyl carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1-dodecyl alcohol (112-53-8) + carbamic acid phenyl ester (622-46-8) → dodecyl carbamate (6320-52-1)

Guidance literature:

With di-n-butyltin maleate; In toluene; at 90 ℃; for 3h;

DOI:10.1055/s-0030-1258102

Reference yield: 97.0%

1-dodecyl alcohol (112-53-8) + methyl carbamate (598-55-0) → dodecyl carbamate (6320-52-1)

Guidance literature:

With di-n-butyltin maleate; In toluene; for 3h; Reflux;

DOI:10.1055/s-0040-1708020

Reference yield: 0.6%

bromocyane (506-68-3) + 1-dodecyl alcohol (112-53-8) → dodecyl carbamate (6320-52-1)

Guidance literature:

With acetyl chloride; 1.) 0 deg C, 2.) roome temperature 30 h, 3.) reflux, 2.5 h;

DOI:10.1016/S0040-4020(01)87238-0

upstream raw materials:

1-dodecyl alcohol

urea

urethane

bromocyane

Refernces

• 1、 Ichikawa, Yoshiyasu,Morishita, Yukinori,Kusaba, Shuhei,Sakiyama, Naoto,Matsuda, Yasunori,Nakano, Keiji,Kotsuki, Hiyoshizo. "An efficient synthesis of carbamates by tin-catalyzed transcarbamoylation reactions of primary and secondary alcohols". experimental part. p. 1815 - 1818. Retrieved 2010/10/05.