[(7-Oxabicyclo[4.1.0]heptan-1-yl)methyl](oxo)diphenyl-lambda~5~-phosphane

Base Information

Chemical Name:[(7-Oxabicyclo[4.1.0]heptan-1-yl)methyl](oxo)diphenyl-lambda~5~-phosphane
CAS No.:87512-44-5
Molecular Formula:C19H21O2P
Molecular Weight:312.348
Hs Code.:
DSSTox Substance ID:DTXSID60519380

Synonyms:87512-44-5;DTXSID60519380;[(7-Oxabicyclo[4.1.0]heptan-1-yl)methyl](oxo)diphenyl-lambda~5~-phosphane

Suppliers and Price of [(7-Oxabicyclo[4.1.0]heptan-1-yl)methyl](oxo)diphenyl-lambda~5~-phosphane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [(7-Oxabicyclo[4.1.0]heptan-1-yl)methyl](oxo)diphenyl-lambda~5~-phosphane

Chemical Property:

XLogP3:3.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:312.12791691
Heavy Atom Count:22
Complexity:415

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1CCC2(C(C1)O2)CP(=O)(C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of [(7-Oxabicyclo[4.1.0]heptan-1-yl)methyl](oxo)diphenyl-lambda~5~-phosphane

There total 5 articles about [(7-Oxabicyclo[4.1.0]heptan-1-yl)methyl](oxo)diphenyl-lambda~5~-phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 76002-40-9
1-(diphenylphosphinoylmethyl)cyclohexene

: 87512-44-5
1-(diphenylphosphinoylmethyl)-7-oxabicyclo<4.1.0>heptane

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid;

Reference yield:

: 87512-43-4
1-(diphenylphosphinoylmethyl)cyclohexanol

: 87512-44-5
1-(diphenylphosphinoylmethyl)-7-oxabicyclo<4.1.0>heptane

Guidance literature:: Multi-step reaction with 2 steps

1: 91 percent / TFA / 1 h / Heating

2: 91 percent / m-chloroperbenzoic acid, sodium carbonate / CH₂Cl₂ / 72 h / Ambient temperature

With sodium carbonate; 3-chloro-benzenecarboperoxoic acid; trifluoroacetic acid; In dichloromethane;

Reference yield:

: 2129-89-7
diphenyl(methyl)phosphine oxide

: 87512-44-5
1-(diphenylphosphinoylmethyl)-7-oxabicyclo<4.1.0>heptane

Guidance literature:: Multi-step reaction with 3 steps

1: 87 percent / BuLi / tetrahydrofuran / 1.) -78 deg C, 10 min, 2.) warm to room temperature

2: 91 percent / TFA / 1 h / Heating

3: 91 percent / m-chloroperbenzoic acid, sodium carbonate / CH₂Cl₂ / 72 h / Ambient temperature

With n-butyllithium; sodium carbonate; 3-chloro-benzenecarboperoxoic acid; trifluoroacetic acid; In tetrahydrofuran; dichloromethane;