[(2-Methylidenecyclohexyl)sulfanyl]benzene

Base Information

Chemical Name:[(2-Methylidenecyclohexyl)sulfanyl]benzene
CAS No.:67957-89-5
Molecular Formula:C13H16S
Molecular Weight:204.336
Hs Code.:
DSSTox Substance ID:DTXSID20519381
Nikkaji Number:J2.217.758C

Synonyms:67957-89-5;[(2-Methylidenecyclohexyl)sulfanyl]benzene;DTXSID20519381

Suppliers and Price of [(2-Methylidenecyclohexyl)sulfanyl]benzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of [(2-Methylidenecyclohexyl)sulfanyl]benzene

Chemical Property:

XLogP3:4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:2
Exact Mass:204.09727168
Heavy Atom Count:14
Complexity:191

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C=C1CCCCC1SC2=CC=CC=C2

Technology Process of [(2-Methylidenecyclohexyl)sulfanyl]benzene

There total 8 articles about [(2-Methylidenecyclohexyl)sulfanyl]benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 110452-14-7
2-phenylthiocyclohexanone

: 1779-49-3
Methyltriphenylphosphonium bromide

: 67957-89-5
1-(phenylthio)-2-(methylene)cyclohexane

Guidance literature:: With potassium tert-butylate; In tetrahydrofuran; for 2h; Heating;
DOI:10.1016/S0040-4020(01)90569-1

Reference yield: 16.0%

: trans-1-(diphenylphosphinoylmethyl)-2-(phenylthio)cyclohexanol

: 67957-89-5
1-(phenylthio)-2-(methylene)cyclohexane

: 2129-89-7
diphenyl(methyl)phosphine oxide

Guidance literature:: With sodium hydride; In tetrahydrofuran; 1.) 0 deg C, 0.5 h, 2.) reflux, 2 h;

Reference yield:

: 1212-08-4
S-Phenyl benzenethiosulfonate

: 67957-89-5
1-(phenylthio)-2-(methylene)cyclohexane

Guidance literature:: Multi-step reaction with 2 steps

1.1: LDA / tetrahydrofuran / 0.67 h / -78 - 0 °C

1.2: 92 percent / tetrahydrofuran / 2 h / -78 °C

2.1: potassium t-butoxide / tetrahydrofuran / 1 h / 20 °C

2.2: 93 percent / tetrahydrofuran / 2 h / Heating

With potassium tert-butylate; lithium diisopropyl amide; In tetrahydrofuran;
DOI:10.1021/ol051049i