(Hexane-1,6-diyl)bis[bromo(diphenyl)stannane]

Base Information

Chemical Name:(Hexane-1,6-diyl)bis[bromo(diphenyl)stannane]
CAS No.:87518-47-6
Molecular Formula:C30H32Br2Sn2
Molecular Weight:789.812
Hs Code.:
DSSTox Substance ID:DTXSID10531219
Wikidata:Q82402914

Synonyms:(Hexane-1,6-diyl)bis[bromo(diphenyl)stannane];87518-47-6;DTXSID10531219

Suppliers and Price of (Hexane-1,6-diyl)bis[bromo(diphenyl)stannane]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (Hexane-1,6-diyl)bis[bromo(diphenyl)stannane]

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:11
Exact Mass:789.88884
Heavy Atom Count:34
Complexity:472

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC=C(C=C1)[Sn](CCCCCC[Sn](C2=CC=CC=C2)(C3=CC=CC=C3)Br)(C4=CC=CC=C4)Br

Technology Process of (Hexane-1,6-diyl)bis[bromo(diphenyl)stannane]

There total 1 articles about (Hexane-1,6-diyl)bis[bromo(diphenyl)stannane] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 5274-41-9
1,6-bis(triphenylstannyl)hexane

: 87518-47-6
1,6-bis(bromodiphenylstannyl)hexane

Guidance literature:: With hydrogen bromide; In dichloromethane; to soln. of Sn compd. added slowly (2 h) soln. of 2.1 equiv of HBr at -78°C, slowly warmed to 25°C, reacted for 8-10 h; evapd. (vac.), chromd. (MeCN or MeCN/THF), crystd. on standing;
DOI:10.1021/om00079a003

Reference yield: 60.0%

: 87518-47-6
1,6-bis(bromodiphenylstannyl)hexane

: 361541-51-7
(6-chlorohexyl)magnesium bromide

: 87518-52-3
1,20-dichloro-7,7,13,13-tetraphenyl-7,13-distannaeicosane

Guidance literature:: With magnesium; In tetrahydrofuran; (N2); to suspn. of Mg at -10°C added over 40 min BrMg(CH2)6Cl soln., stirred for 30 min at 25°C and 60 min at 0°C, dilutedwith THF, added over 1.5 h soln. of Sn compd. at 0°C, warmed slowly, reacted for 7 h at 25°C; quenched with satd. aq. NH4Cl, aq. layer extd. (ether), combined org. layers washed (satd. aq. NaCl), dried (MgSO4), concd. (vac.), chromd. (MeCN/THF);
DOI:10.1021/om00079a003

Reference yield: 26.0%

: 629-03-8
1 ,6-dibromohexane

: 87518-47-6
1,6-bis(bromodiphenylstannyl)hexane

: 87518-40-9
1,1,8,8,15,15,22,22-octaphenyl-1,8,15,22-tetrastannacyclooctacosane

: 87518-36-3
1,1,8,8-tetraphenyl-1,8-distannacyclotetradecane

Guidance literature:: With iodine; magnesium; In tetrahydrofuran; (N2); to suspn. of Mg and I2 at 25°C added over 1 h soln. of Br(CH2)6Br, stirred for 4 h, sepd. from excess of Mg, diluted with THF, added over 2.5 h to Sn-compd. soln. at 0°C, allowed to warm to 25°C, stirred for 10 h; satd. aq. NH4Cl added at 0°C, aq. layer extd. (ether), combined ethereal solns. washed (satd. aq. NaCl), dried (MgSO4), filtered, concd., chromd. (MeCN/THF), recrystd. (hexane); elem. anal.;
DOI:10.1021/om00079a003