(Decane-1,10-diyl)bis[bromo(diphenyl)stannane]

Base Information

Chemical Name:(Decane-1,10-diyl)bis[bromo(diphenyl)stannane]
CAS No.:87518-49-8
Molecular Formula:C34H40Br2Sn2
Molecular Weight:845.92
Hs Code.:
DSSTox Substance ID:DTXSID80531221
Wikidata:Q82402918

Synonyms:(Decane-1,10-diyl)bis[bromo(diphenyl)stannane];87518-49-8;DTXSID80531221

Suppliers and Price of (Decane-1,10-diyl)bis[bromo(diphenyl)stannane]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (Decane-1,10-diyl)bis[bromo(diphenyl)stannane]

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:15
Exact Mass:845.95144
Heavy Atom Count:38
Complexity:526

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)[Sn](CCCCCCCCCC[Sn](C2=CC=CC=C2)(C3=CC=CC=C3)Br)(C4=CC=CC=C4)Br

Technology Process of (Decane-1,10-diyl)bis[bromo(diphenyl)stannane]

There total 1 articles about (Decane-1,10-diyl)bis[bromo(diphenyl)stannane] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 87518-44-3
1,10-bis(triphenylstannyl)decane

: 87518-49-8
1,12-dibromo-1,1,12,12-tetraphenyl-1,12-distannadodecane

Guidance literature:: With hydrogen bromide; In dichloromethane; to soln. of Sn compd. added slowly (2 h) soln. of 2.1 equiv of HBr at -78°C, slowly warmed to 25°C, reacted for 8-10 h; evapd. (vac.), chromd. (MeCN or MeCN/THF);
DOI:10.1021/om00079a003

Reference yield: 78.0%

: 693-03-8
n-butyl magnesium bromide

: 87518-49-8
1,12-dibromo-1,1,12,12-tetraphenyl-1,12-distannadodecane

: 105162-91-2
5,5,16,16-tetraphenyl-5,16-distannaeicosane

Guidance literature:: In tetrahydrofuran; to a stirred soln. of Sn-compound in THF at 0°C under nitrogen was added over 1.25 h a soln. of butylmagnesiumbromide, soln. was allowed to reach room temp. overnight; satd. aq. NH4Cl soln. was added at 0°C, aq. layer extd. with ether, org. phases washed with brine, dried, evapd., residue was purified by reverse phase chromy. (eluant MeOH/THF (3.5/1)); elem. anal.;

Reference yield: 26.0%

: 87518-49-8
1,12-dibromo-1,1,12,12-tetraphenyl-1,12-distannadodecane

: 4101-68-2
1,10-dibromodecane

: 87518-42-1
1,1,12,12,23,23,34,34-octaphenyl-1,12,23,34-tetrastannacyclotetratetracontane

: 87518-37-4
1,1,12,12-tetraphenyl-1,12-distannacyclodocosane

Guidance literature:: With iodine; magnesium; In tetrahydrofuran; (N2); to suspn. of Mg and I2 at 25°C added over 1 h soln. of Br(CH2)10Br, stirred for 4 h, sepd. from excess of Mg, diluted with THF, added over 2.5 h to Sn-compd. soln. at 0°C, allowed to warm to 25°C, stirred for 10 h; satd. aq. NH4Cl added at 0°C, aq. layer extd. (ether), combined ethereal solns. washed (satd. aq. NaCl), dried (MgSO4), filtered, concd., chromd. (MeCN/THF), recrystd. (hexane or EtOH); elem. anal.;
DOI:10.1021/om00079a003