4101-68-2

Basic information

• Product Name: 1,10-Dibromodecane
• Synonyms: DECAMETHYLENE BROMIDE;DECAMETHYLENE DIBROMIDE;Dibromodecane,95%;Decane, 1,10-dibromo-;1,10-Dibromodecane,97%;1,10-Dibromodecane,Decamethylene dibromide;1,10-DibroModecane, 97% 100ML;1,10-DibroModecane, 97% 25ML
• CAS NO: 4101-68-2
• Molecular Formula: C₁₀H₂₀Br₂
• Molecular Weight: 300.07
• EINECS: 223-871-0
• Product Categories: DIBROMOALKANE;Bromine Compounds;alpha,omega-Bifunctional Alkanes;alpha,omega-Dibromoalkanes;Monofunctional & alpha,omega-Bifunctional Alkanes
• Mol File: 4101-68-2.mol
• Article Data: 18

Chemical Properties

• Melting Point: 25-27 °C(lit.)
• Boiling Point: 160 °C15 mm Hg(lit.)
• Flash Point: 26°C
• Appearance: Beige to brown/Crystalline Low Melting Solid
• Density: 1.335 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.00233mmHg at 25°C
• Refractive Index: n20/D 1.4912(lit.)
• Storage Temp.: 2-8°C
• Water Solubility: insoluble
• BRN: 506156
• CAS DataBase Reference: 1,10-Dibromodecane(CAS DataBase Reference)
• NIST Chemistry Reference: 1,10-Dibromodecane(4101-68-2)
• EPA Substance Registry System: 1,10-Dibromodecane(4101-68-2)

Safety Data

• Hazard Codes: C,Xi
• Statements: 20/21/22-36/37/38
• Safety Statements: 22-24/25-36-26
• WGK Germany: 3
• TSCA: Yes
• Hazardous Substances Data: 4101-68-2(Hazardous Substances Data)

Usage

Chemical Properties

beige to brown crystalline low melting mass

Uses

1,10-Dibromodecane is used as an alkylating agent and as synthetic organic intermediate.

InChI:InChI=1/C10H20Br2/c11-9-7-5-3-1-2-4-6-8-10-12/h1-10H2

Upstream product

• 4117-09-3 7-bromo-hept-1-ene 
• 1373139-23-1 C₇H₁₃BrO₃ 
• 140-88-5 ethyl acrylate 
• 112-47-0 1,10-Decanediol 
• 2834-05-1 11-bromoundecanoic acid 
• 1647-16-1 1,10-decadiene 
• 497-19-8 sodium carbonate 
• 110-40-7 diethyl sebacate 
• 749879-21-8 1-(10-bromo-decyloxy)-2-methoxy-benzene 
• 10035-10-6 hydrogen bromide 
• 64-19-7 acetic acid 
• 111-24-0 1,5-dibromo-pentane 
• 4224-70-8 6-bromohexanoic acid 
• 818-88-2 sebacic acid mono methyl ester 

Downstream Products

• 1465-74-3 1,10-bis(isoquinolinium)decane dibromide 
• 118160-73-9 1-(10-Bromo-decyl)-4-[(E)-2-(4-hydroxy-phenyl)-vinyl]-pyridinium; bromide 
• 6275-34-9 4,4'-dimethyl-1,1'-decanediyl-bis-pyridinium; dibromide 
• 6266-40-6 decamethylene bis(pyridinium bromide) 
• 186043-25-4 4-[(10-bromodecyl)oxy]-3-methoxybenzaldehyde 
• 88088-72-6 (((10-bromodecyl)oxy)methyl)benzene 
• 917-20-4 Decamethylene-1,10-bis(triphenylphosphonium bromide) 
• 115291-37-7 3,3'-[decane-1,10-diylbis(oxy)]dibenzaldehyde 
• 188180-39-4 2-(16-benzyloxyhexadec-1-yl)bromide 
• 221656-53-7 N,N-dimethyl-10-phenyldecylamine 
• 172846-35-4 di-tert-butyl 10-bromodecylamine-N,N-dicarboxylate 
• 52251-33-9 2,5-Bis-(10-bromo-decyloxy)-terephthalonitrile 
• 52251-31-7 1,4-Bis-(10-bromdecyloxy)-2,5-dibrombenzol 
• 34728-11-5 C₅₀H₈₆O₆ 

Relevant articles and documents

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Acid monolayer functionalized iron oxide nanoparticles as catalysts for carbohydrate hydrolysis

Superparamagnetic iron oxide nanoparticles were functionalized with a quasi-monolayer of 11-sulfoundecanoic acid and 10-phosphono-1-decanesulfonic acid ligands to create separable solid acid catalysts. The ligands are bound through carboxylate or phosphonate bonds to the magnetite core. The ligand-core bonding surface is separated by a hydrocarbon linker from an outer surface with exposed sulfonic acid groups. The more tightly packed monolayer of the phosphonate ligand corresponded to a higher sulfonic acid loading by weight, a reduced agglomeration of particles, a greater tendency to remain suspended in solution in the presence of an external magnetic field, and a higher catalytic activity per sulfonic acid group. The particles were characterized by thermogravimetric analysis (TGA), transmission electron microscopy (TEM), potentiometric titration, diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), inductively coupled plasma optical emission spectrometry (ICP-OES), and dynamic light scattering (DLS). In sucrose catalysis reactions, the phosphonic-sulfonic nanoparticles (PSNPs) were seen to be incompletely recovered by an external magnetic field, while the carboxylic-sulfonic nanoparticles (CSNPs) showed a trend of increasing activity over the first four recycle runs. The activity of the acid-functionalized nanoparticles was compared to the traditional solid acid catalyst Amberlyst-15 for the hydrolysis of starch in aqueous solution. Catalytic activity for starch hydrolysis was in the order PSNPs > CSNPs > Amberlyst-15. Monolayer acid functionalization of iron oxides presents a novel strategy for the development of recyclable solid acid catalysts.

PROCESS FOR THE PREPARATION OF ORGANIC BROMIDES

The present invention provides a process for the preparation of organic bromides, by a radical bromodecarboxylation of carboxylic acids with a bromoisocyanurate.

Catalytic Access to Alkyl Bromides, Chlorides and Iodides via Visible Light-Promoted Decarboxylative Halogenation

Herein is reported the catalytic, visible light-promoted, decarboxylative halogenation (bromination, chlorination, and iodination) of aliphatic carboxylic acids. This operationally-simple reaction tolerates a range of functional groups, proceeds at room temperature, and is redox neutral. By employing an iridium photocatalyst in concert with a halogen atom source, the use of stoichiometric metals such as silver, mercury, thallium, and lead can be circumvented. This reaction grants access to valuable synthetic building blocks from the large pool of cheap, readily available carboxylic acids.