4,11,13-Pentadecatrienoic acid, 3,7-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-10-methoxy-4,6,14-trimethyl -9-oxo-15-[3-[[[2-(trimethylsilyl)ethoxy]carbonyl]amino]-5-[[[2-(trimethylsil yl)ethoxy]carbonyl]oxy]phenyl]-, (3S,4E,6S,7S,10R,11E,13E)-

Base Information

Chemical Name:4,11,13-Pentadecatrienoic acid, 3,7-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-10-methoxy-4,6,14-trimethyl -9-oxo-15-[3-[[[2-(trimethylsilyl)ethoxy]carbonyl]amino]-5-[[[2-(trimethylsil yl)ethoxy]carbonyl]oxy]phenyl]-, (3S,4E,6S,7S,10R,11E,13E)-
CAS No.:875439-82-0
Molecular Formula:C49H87NO11Si4
Molecular Weight:978.572
Hs Code.:

4,11,13-Pentadecatrienoic acid,
3,7-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-10-methoxy-4,6,14-trimethyl
-9-oxo-15-[3-[[[2-(trimethylsilyl)ethoxy]carbonyl]amino]-5-[[[2-(trimethylsil
yl)ethoxy]carbonyl]oxy]phenyl]-, (3S,4E,6S,7S,10R,11E,13E)-

Synonyms:

Suppliers and Price of 4,11,13-Pentadecatrienoic acid, 3,7-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-10-methoxy-4,6,14-trimethyl -9-oxo-15-[3-[[[2-(trimethylsilyl)ethoxy]carbonyl]amino]-5-[[[2-(trimethylsil yl)ethoxy]carbonyl]oxy]phenyl]-, (3S,4E,6S,7S,10R,11E,13E)-

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Chemical Property of 4,11,13-Pentadecatrienoic acid, 3,7-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-10-methoxy-4,6,14-trimethyl -9-oxo-15-[3-[[[2-(trimethylsilyl)ethoxy]carbonyl]amino]-5-[[[2-(trimethylsil yl)ethoxy]carbonyl]oxy]phenyl]-, (3S,4E,6S,7S,10R,11E,13E)-

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Technology Process of 4,11,13-Pentadecatrienoic acid, 3,7-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-10-methoxy-4,6,14-trimethyl -9-oxo-15-[3-[[[2-(trimethylsilyl)ethoxy]carbonyl]amino]-5-[[[2-(trimethylsil yl)ethoxy]carbonyl]oxy]phenyl]-, (3S,4E,6S,7S,10R,11E,13E)-

There total 23 articles about 4,11,13-Pentadecatrienoic acid, 3,7-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-10-methoxy-4,6,14-trimethyl -9-oxo-15-[3-[[[2-(trimethylsilyl)ethoxy]carbonyl]amino]-5-[[[2-(trimethylsil yl)ethoxy]carbonyl]oxy]phenyl]-, (3S,4E,6S,7S,10R,11E,13E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 875439-81-9
Carbonic acid 3-[(2E,4E,11E)-(6R,9S,10S,13S)-9,13-bis-(tert-butyl-dimethyl-silanyloxy)-6-methoxy-2,10,12-trimethyl-7,15-dioxo-pentadeca-2,4,11-trienyl]-5-(2-trimethylsilanyl-ethoxycarbonylamino)-phenyl ester 2-trimethylsilanyl-ethyl ester

: 875439-82-0
(4E,11E,13E)-(3S,6S,7S,10R)-3,7-Bis-(tert-butyl-dimethyl-silanyloxy)-10-methoxy-4,6,14-trimethyl-9-oxo-15-[3-(2-trimethylsilanyl-ethoxycarbonylamino)-5-(2-trimethylsilanyl-ethoxycarbonyloxy)-phenyl]-pentadeca-4,11,13-trienoic acid

Guidance literature:: With sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; In water; tert-butyl alcohol; for 1h;
DOI:10.1021/ol052588q

Reference yield:

: 875439-73-9
3-amino-5-[(E)-3-iodo-2-methylprop-2-enyl]-phenol

: 875439-82-0
(4E,11E,13E)-(3S,6S,7S,10R)-3,7-Bis-(tert-butyl-dimethyl-silanyloxy)-10-methoxy-4,6,14-trimethyl-9-oxo-15-[3-(2-trimethylsilanyl-ethoxycarbonylamino)-5-(2-trimethylsilanyl-ethoxycarbonyloxy)-phenyl]-pentadeca-4,11,13-trienoic acid

Guidance literature:: Multi-step reaction with 4 steps

1: 89 percent / pyridine / CH₂Cl₂ / 0 °C

2: 72 percent / tetrabutylammonium bromide; cesium carbonate; triethylamine / Pd(OAc)2 / dimethylformamide / 3 h

3: 83 percent / oxalyl chloride; triethylamine / dimethylsulfoxide; CH₂Cl₂ / -60 - -40 °C

4: 99 percent / NaClO₂; NaH₂PO₄*H₂O; 2-methyl-2-butene / 2-methyl-propan-2-ol; H₂O / 1 h

With pyridine; sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; oxalyl dichloride; tetrabutylammomium bromide; caesium carbonate; triethylamine; palladium diacetate; In dichloromethane; water; dimethyl sulfoxide; N,N-dimethyl-formamide; tert-butyl alcohol; 2: Heck reaction;
DOI:10.1021/ol052588q

Reference yield:

: (E)-3-(3-amino-5-hydroxy-phenyl)-2-methyl-prop-1-ene

: 875439-82-0
(4E,11E,13E)-(3S,6S,7S,10R)-3,7-Bis-(tert-butyl-dimethyl-silanyloxy)-10-methoxy-4,6,14-trimethyl-9-oxo-15-[3-(2-trimethylsilanyl-ethoxycarbonylamino)-5-(2-trimethylsilanyl-ethoxycarbonyloxy)-phenyl]-pentadeca-4,11,13-trienoic acid

Guidance literature:: Multi-step reaction with 5 steps

1: 615 mg / I₂ / 1,2-dichloro-ethane; hexane; tetrahydrofuran / 1 h / -30 °C

2: 89 percent / pyridine / CH₂Cl₂ / 0 °C

3: 72 percent / tetrabutylammonium bromide; cesium carbonate; triethylamine / Pd(OAc)2 / dimethylformamide / 3 h

4: 83 percent / oxalyl chloride; triethylamine / dimethylsulfoxide; CH₂Cl₂ / -60 - -40 °C

5: 99 percent / NaClO₂; NaH₂PO₄*H₂O; 2-methyl-2-butene / 2-methyl-propan-2-ol; H₂O / 1 h

With pyridine; sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; oxalyl dichloride; tetrabutylammomium bromide; iodine; caesium carbonate; triethylamine; palladium diacetate; In tetrahydrofuran; hexane; dichloromethane; water; dimethyl sulfoxide; 1,2-dichloro-ethane; N,N-dimethyl-formamide; tert-butyl alcohol; 3: Heck reaction;
DOI:10.1021/ol052588q