1,3-Propanediol, 2-[(triphenylstannyl)methyl]-, dimethanesulfonate

Base Information

Chemical Name:1,3-Propanediol, 2-[(triphenylstannyl)methyl]-, dimethanesulfonate
CAS No.:87597-81-7
Molecular Formula:C24H28O6S2Sn
Molecular Weight:595.32
Hs Code.:

Synonyms:2-[(triphenylstannyl)methyl]-1,3-propanediol dimethanesulfonate;1,3-Propanediol,2-[(triphenylstannyl)methyl]-,dimethanesulfonate;

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1,3-Propanediol, 2-[(triphenylstannyl)methyl]-, dimethanesulfonate

Chemical Property:

PSA：165.96000
LogP:4.13510

Purity/Quality:

Safty Information:

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Technology Process of 1,3-Propanediol, 2-[(triphenylstannyl)methyl]-, dimethanesulfonate

There total 1 articles about 1,3-Propanediol, 2-[(triphenylstannyl)methyl]-, dimethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.2%

: 87597-80-6
2-[(triphenylstannyl)methyl]-1,3-propanediol

: 124-63-0
methanesulfonyl chloride

: 87597-81-7
2-[(triphenylstannyl)methyl]-1,3-propanediol dimethanesulfonate

Guidance literature:: With triethylamine; In dichloromethane; stirred soln. of Sn educt and (C2H5)3N treated dropwise with methanesulfonyl chloride at 0°C, kept at 0°C for 4 h; dild. with CH2Cl2, washed at 0°C with H2O, aq. HCl, satd. aq. NaHCO3, org. phase dried, evapd. (vac.), crystd. (hexanes/C6H6); elem. anal.;

Reference yield: 76.9%

: 4167-90-2
triphenylstannyllithium

: 87597-81-7
2-[(triphenylstannyl)methyl]-1,3-propanediol dimethanesulfonate

: 87549-81-3
tris[(triphenylstannyl)methyl]methane

Guidance literature:: In tetrahydrofuran; under dry Ar at 0°C, stirred soln. of (C6H5)3SnLi treated dropwise with soln. of (C6H5)3SnCH2CH(CH2OSO2CH3)2, kept at 25°C for 18h, refluxed for 3 h; H2O added, evapd. (vac.), partitioned between H2O and CH2Cl2, org. phase dried, evapd. (vac.), chromd. (SiO2, hexanes/CHCl3), crystd. (hexanes/EtOAc); elem. anal.;