5-Heptenoic acid, 7-[(1R,5S)-2-oxo-5-[4-[1-(phenylmethoxy)hexyl]phenyl]cyclopentyl]-, (5Z)-

Base Information

Chemical Name:5-Heptenoic acid, 7-[(1R,5S)-2-oxo-5-[4-[1-(phenylmethoxy)hexyl]phenyl]cyclopentyl]-, (5Z)-
CAS No.:879098-92-7
Molecular Formula:C31H40O4
Molecular Weight:476.656
Hs Code.:

Synonyms:

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Chemical Property of 5-Heptenoic acid, 7-[(1R,5S)-2-oxo-5-[4-[1-(phenylmethoxy)hexyl]phenyl]cyclopentyl]-, (5Z)-

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Technology Process of 5-Heptenoic acid, 7-[(1R,5S)-2-oxo-5-[4-[1-(phenylmethoxy)hexyl]phenyl]cyclopentyl]-, (5Z)-

There total 9 articles about 5-Heptenoic acid, 7-[(1R,5S)-2-oxo-5-[4-[1-(phenylmethoxy)hexyl]phenyl]cyclopentyl]-, (5Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 879098-70-1
(Z)-7-{(1R,2S,5S)-2-[4-(1-Benzyloxy-hexyl)-phenyl]-5-hydroxy-cyclopentyl}-hept-5-enoic acid

: 879098-92-7
(Z)-7-{(1R,2S)-2-[4-(1-Benzyloxy-hexyl)-phenyl]-5-oxo-cyclopentyl}-hept-5-enoic acid

Guidance literature:: With pyridinium chlorochromate; In dichloromethane; at 20 ℃; for 1h;
DOI:10.1021/ja057560o

Reference yield:

: 879098-65-4
Acetic acid (1R,4S)-4-(1-butoxy-2-iodo-ethoxy)-cyclopent-2-enyl ester

: 879098-92-7
(Z)-7-{(1R,2S)-2-[4-(1-Benzyloxy-hexyl)-phenyl]-5-oxo-cyclopentyl}-hept-5-enoic acid

Guidance literature:: Multi-step reaction with 7 steps

1.1: CoCl₂; (R,R)-1,2-bis(dimethylamino)cyclohexane / tetrahydrofuran / 0.25 h / 25 °C

1.2: 54 percent / Jones reagent / acetone / 20 °C

2.1: 85 percent / K₂CO₃ / methanol / 0.5 h / 20 °C

3.1: pyridine; N,N-dimethyl-4-aminopyridine / CH₂Cl₂ / 12 h / 20 °C

4.1: 235 mg / AIBN; (Me₃Si)3SiH / toluene / 1 h / Heating

5.1: 84 percent / DIBAL-H / toluene; hexane / 0.5 h / -60 °C

6.1: sodium hexamethyldisilazide / tetrahydrofuran / 0 - 20 °C

6.2: 87 percent / tetrahydrofuran / 1 h / 20 °C

7.1: 50 percent / pyridinium chlorochromate / CH₂Cl₂ / 1 h / 20 °C

With pyridine; dmap; 2,2'-azobis(isobutyronitrile); tris-(trimethylsilyl)silane; (1R,2R)-bis(dimethylamino)cyclohexane; sodium hexamethyldisilazane; diisobutylaluminium hydride; potassium carbonate; pyridinium chlorochromate; In tetrahydrofuran; methanol; hexane; dichloromethane; toluene;
DOI:10.1021/ja057560o

Reference yield:

: C₁₉H₂₃BrMgO

: 879098-92-7
(Z)-7-{(1R,2S)-2-[4-(1-Benzyloxy-hexyl)-phenyl]-5-oxo-cyclopentyl}-hept-5-enoic acid

Guidance literature:: Multi-step reaction with 7 steps

1.1: CoCl₂; (R,R)-1,2-bis(dimethylamino)cyclohexane / tetrahydrofuran / 0.25 h / 25 °C

1.2: 54 percent / Jones reagent / acetone / 20 °C

2.1: 85 percent / K₂CO₃ / methanol / 0.5 h / 20 °C

3.1: pyridine; N,N-dimethyl-4-aminopyridine / CH₂Cl₂ / 12 h / 20 °C

4.1: 235 mg / AIBN; (Me₃Si)3SiH / toluene / 1 h / Heating

5.1: 84 percent / DIBAL-H / toluene; hexane / 0.5 h / -60 °C

6.1: sodium hexamethyldisilazide / tetrahydrofuran / 0 - 20 °C

6.2: 87 percent / tetrahydrofuran / 1 h / 20 °C

7.1: 50 percent / pyridinium chlorochromate / CH₂Cl₂ / 1 h / 20 °C

With pyridine; dmap; 2,2'-azobis(isobutyronitrile); tris-(trimethylsilyl)silane; (1R,2R)-bis(dimethylamino)cyclohexane; sodium hexamethyldisilazane; diisobutylaluminium hydride; potassium carbonate; pyridinium chlorochromate; In tetrahydrofuran; methanol; hexane; dichloromethane; toluene;
DOI:10.1021/ja057560o