2-(Phenylselanyl)benzaldehyde

Base Information

• Chemical Name: 2-(Phenylselanyl)benzaldehyde
• CAS No.: 88048-84-4
• Molecular Formula: C13H10OSe
• Molecular Weight: 261.182
• DSSTox Substance ID: DTXSID70525533
• Nikkaji Number: J314.907B
• Wikidata: Q82393205
• Mol file: 88048-84-4.mol

Synonyms:2-(Phenylselanyl)benzaldehyde;88048-84-4;DTXSID70525533

Chemical Property of 2-(Phenylselanyl)benzaldehyde

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 261.98969
• Heavy Atom Count: 15
• Complexity: 199

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Se]C2=CC=CC=C2C=O

Technology Process of 2-(Phenylselanyl)benzaldehyde

There total 12 articles about 2-(Phenylselanyl)benzaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

diphenyl diselenide (1666-13-3) + 2-formylbenzene boronic acid (40138-16-7) → 2-formylphenyl phenyl selenide (88048-84-4)

Guidance literature:

With Cu NPs/Ac; In dimethyl sulfoxide; at 20 - 100 ℃; for 9h; Sealed tube; Sonication;

Reference yield: 86.1%

sodium phenylselenide (23974-72-3) + 2-chloro-benzaldehyde (89-98-5) → 2-formylphenyl phenyl selenide (88048-84-4)

Guidance literature:

In N,N-dimethyl-formamide; at 120 ℃; for 4h;

Reference yield: 85.0%

2-iodophenyl 4-chlorobenzenesulfonate (864512-14-1) + Benzeneselenol (645-96-5) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → 2-formylphenyl phenyl selenide (88048-84-4)

Guidance literature:

Benzeneselenol; With isopropylmagnesium chloride; In tetrahydrofuran; at -20 ℃; for 0.5h;

2-iodophenyl 4-chlorobenzenesulfonate; With isopropylmagnesium chloride; In tetrahydrofuran; at -78 - 0 ℃;

N,N-dimethyl-formamide; In tetrahydrofuran; at -40 - 20 ℃;

DOI:10.1002/anie.200500443

upstream raw materials:

sodium phenylselenide

2-chloro-benzaldehyde

1-chloro-1-phenyl-3H-2,1-benzoxaselenole

phenyllithium

Downstream raw materials:

2-(phenylseleno)phenylpentadeuteriophenylmethanol

phenyl[o-(phenylseleno)phenyl]methanol

9H-selenoxanthene

selenoxanthen-9-one