2-Formylphenylboronic acid

Base Information

Chemical Name:2-Formylphenylboronic acid
CAS No.:40138-16-7
Molecular Formula:C7H7BO3
Molecular Weight:149.942
Hs Code.:2931900090
European Community (EC) Number:628-526-1
NSC Number:157839
UNII:MT69HY4FNF
DSSTox Substance ID:DTXSID30901733
Nikkaji Number:J1.082.419B
Wikidata:Q106902657
ChEMBL ID:CHEMBL139725
Mol file:40138-16-7.mol

Synonyms:2-formylphenylboronic acid;o-formylphenylboronic acid

Suppliers and Price of 2-Formylphenylboronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
2-Formylphenylboronic acid
100mg
$ 70.00

TCI Chemical
2-Formylphenylboronic Acid (contains varying amounts of Anhydride)
5g
$ 81.00

TCI Chemical
2-Formylphenylboronic Acid (contains varying amounts of Anhydride)
1g
$ 28.00

SynQuest Laboratories
2-Formylbenzeneboronic acid 97%
5 g
$ 24.00

SynQuest Laboratories
2-Formylbenzeneboronic acid 97%
100 g
$ 274.00

SynQuest Laboratories
2-Formylbenzeneboronic acid 97%
25 g
$ 72.00

Sigma-Aldrich
2-Formylphenylboronic acid ≥95.0%
5g
$ 110.00

Sigma-Aldrich
2-Formylphenylboronic acid ≥95.0%
1g
$ 39.40

Oakwood
2-Formylbenzeneboronic acid
5g
$ 10.00

Oakwood
2-Formylbenzeneboronic acid
1g
$ 9.00

Total 137 raw suppliers

Chemical Property of 2-Formylphenylboronic acid

Chemical Property:

Appearance/Colour:light yellow to tan powder
Vapor Pressure:1.12E-05mmHg at 25°C
Melting Point:115-120 °C(lit.)
Refractive Index:1.547
Boiling Point:355.7 °C at 760 mmHg
PKA:8.18±0.53(Predicted)
Flash Point:169 °C
PSA：57.53000
Density:1.24 g/cm³
LogP:-0.82110
Storage Temp.:0-6°C
Sensitive.:Air Sensitive
Solubility.:Soluble in methanol.
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:150.0488242
Heavy Atom Count:11
Complexity:138

Purity/Quality:

99% ^*data from raw suppliers

2-Formylphenylboronic acid ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26-36

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B(C1=CC=CC=C1C=O)(O)O
Uses suzuki reaction 2-Formylbenzeneboronic acid is used as an organic chemical synthesis intermediate.

Technology Process of 2-Formylphenylboronic acid

There total 27 articles about 2-Formylphenylboronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 380151-85-9
2-(2'-formylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 40138-16-7
2-formylbenzene boronic acid

Guidance literature:: 2-(2'-formylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane; With potassium hydrogen difluoride; In methanol; at 20 ℃; for 0.25h;

With lithium hydroxide; In acetonitrile; at 20 ℃; for 20h;
DOI:10.1016/j.tetlet.2005.09.101

Reference yield: 83.0%

: 35364-86-4
2-chlorobenzaldehyde diethyl acetal

: 40138-16-7
2-formylbenzene boronic acid

Guidance literature:

Reference yield: 68.0%

: 34824-58-3
2-(2-bromophenyl)-1,3-dioxolan

: 121-43-7,63156-11-6
Trimethyl borate

: 40138-16-7
2-formylbenzene boronic acid

Guidance literature:: With Mg and MeMgBr; aq. HCl; aq. NaOH; In tetrahydrofuran; (Ar); stirring dioxolane with Mg and MeMgBr (room temp., 30 min), heating at reflux (4 h), cooling (0°C), adding precooled (-78°C)B(OMe)3, stirring (4 h), warming (room temp., overnight), treating with aq. HCl; layers sepn., extn. of aq. layer (ether), extn. of ether ext. (aq. NaOH), acidification (aq. HCl, pH=3), extn. (ether), drying (MgSO4), evapn.;
DOI:10.1021/ja963784i