1,3-Dimethyl 2-[(2E)-1-phenyl-2-buten-1-yl]propanedioate

Base Information

Chemical Name:1,3-Dimethyl 2-[(2E)-1-phenyl-2-buten-1-yl]propanedioate
CAS No.:88057-05-0
Molecular Formula:C15H18O4
Molecular Weight:262.306
Hs Code.:
DSSTox Substance ID:DTXSID901200476
Nikkaji Number:J1.250.661I,J746.576I

Synonyms:DTXSID901200476;88057-05-0;1,3-Dimethyl 2-[(2E)-1-phenyl-2-buten-1-yl]propanedioate

Suppliers and Price of 1,3-Dimethyl 2-[(2E)-1-phenyl-2-buten-1-yl]propanedioate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of 1,3-Dimethyl 2-[(2E)-1-phenyl-2-buten-1-yl]propanedioate

Chemical Property:

XLogP3:3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:7
Exact Mass:262.12050905
Heavy Atom Count:19
Complexity:313

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC=CC(C1=CC=CC=C1)C(C(=O)OC)C(=O)OC
Isomeric SMILES:C/C=C/C(C1=CC=CC=C1)C(C(=O)OC)C(=O)OC

Technology Process of 1,3-Dimethyl 2-[(2E)-1-phenyl-2-buten-1-yl]propanedioate

There total 14 articles about 1,3-Dimethyl 2-[(2E)-1-phenyl-2-buten-1-yl]propanedioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 18424-76-5
dimethyl malonate sodium salt

: 100017-26-3
(R)-(Z)-3-acetoxy-1-phenyl-1-butene

: 88057-04-9
(S,E)-2-(1-methyl-3-phenyl-allyl)malonic acid dimethyl ester

: 88057-05-0
<1-phenyl-2-(E)-butenyl>malonate

Guidance literature:: With bis(η3-allyl-μ-chloropalladium(II)); 1,2-bis-(diphenylphosphino)ethane; In tetrahydrofuran; for 20h; Product distribution; Mechanism; Ambient temperature; other acetates, nucleophiles, and palladium catalysts;
DOI:10.1021/jo00355a025

Reference yield:

: 51801-01-5,87246-94-4,97996-32-2,100017-27-4,100017-28-5,108033-84-7,146566-19-0,146566-20-3,79594-08-4
(E)-1-acetoxy-1-phenyl-2-butene

: 108-59-8
malonic acid dimethyl ester

: 200191-40-8
(E)-dimethyl 2-(4-phenylbut-3-en-2-yl)malonate

: 88057-05-0
<1-phenyl-2-(E)-butenyl>malonate

Guidance literature:: With bis(η3-allyl-μ-chloropalladium(II)); sodium hydride; 1,2-bis-(diphenylphosphino)ethane; Yield given. Multistep reaction. Yields of byproduct given; 1.) THF, 0 deg C, 2.) THF, RT, 20 h;
DOI:10.1021/jo00355a025

Reference yield:

: 18424-76-5
dimethyl malonate sodium salt

: 87802-76-4
Carbonic acid methyl ester (E)-1-phenyl-but-2-enyl ester

: 200191-40-8
(E)-dimethyl 2-(4-phenylbut-3-en-2-yl)malonate

: 88057-05-0
<1-phenyl-2-(E)-butenyl>malonate

Guidance literature:: With [2,2]bipyridinyl; tricarbonyl-tris(acetonitrile)tungsten⁽⁰⁾; In tetrahydrofuran; for 4h; Heating;
DOI:10.1021/ja00364a055