N-(But-3-yn-1-yl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine

Base Information

• Chemical Name: N-(But-3-yn-1-yl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine
• CAS No.: 88211-47-6
• Molecular Formula: C10H23NSi2
• Molecular Weight: 213.47
• DSSTox Substance ID: DTXSID90537017
• Wikidata: Q82411857
• Mol file: 88211-47-6.mol

Synonyms:88211-47-6;DTXSID90537017;N-(But-3-yn-1-yl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine;(but-3-yn-1-yl)bis(trimethylsilyl)amine;EN300-39913803

Chemical Property of N-(But-3-yn-1-yl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 213.13690281
• Heavy Atom Count: 13
• Complexity: 187

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)N(CCC#C)[Si](C)(C)C

Technology Process of N-(But-3-yn-1-yl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine

There total 1 articles about N-(But-3-yn-1-yl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-Hexyloxymethyl-1,1,1,3,3,3-hexamethyl-disilazane (88211-45-4) → Hexyloxy-magnesiumbromid + 1-butin-3 (88211-47-6)

Guidance literature:

In diethyl ether; for 12h;

Reference yield: 52.0%

ethyl 2‐(4‐(tert‐butyl)phenyl)2‐oxoacetate (80120-36-1) + 1-butin-3 (88211-47-6) → ethyl 2-(but-3-ynylimino)-2-(4-tert-butylphenyl)acetate

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at 60 ℃; for 72h; Inert atmosphere;

DOI:10.1021/acs.orglett.7b02627

Reference yield:

1-butin-3 (88211-47-6) → Hexamethyldisiloxane (107-46-0) + 4-amino-1-butyne hydrochloride (88211-50-1)

Guidance literature:

With hydrogenchloride; water; In diethyl ether; Yield given;

upstream raw materials:

2-Hexyloxymethyl-1,1,1,3,3,3-hexamethyl-disilazane

Downstream raw materials:

Hexamethyldisiloxane

4-amino-1-butyne hydrochloride