3-methyl-3-(2,2,3,3,3-pentafluoropropoxymethyl)oxetane

Base Information

Chemical Name:3-methyl-3-(2,2,3,3,3-pentafluoropropoxymethyl)oxetane
CAS No.:449177-94-0
Molecular Formula:C₈H₁₁F₅O₂
Molecular Weight:234.166
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3-methyl-3-(2,2,3,3,3-pentafluoropropoxymethyl)oxetane

Chemical Property:

Vapor Pressure:2.86mmHg at 25°C
Boiling Point:162.2°C at 760 mmHg
Flash Point:58°C
PSA：0.00000
Density:1.267g/cm³
LogP:0.00000

Purity/Quality:

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Technology Process of 3-methyl-3-(2,2,3,3,3-pentafluoropropoxymethyl)oxetane

There total 4 articles about 3-methyl-3-(2,2,3,3,3-pentafluoropropoxymethyl)oxetane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 78385-26-9
3-bromomethyl-3-methyloxetane

: 422-05-9
2,2,3,3,3-pentafluoropropyl alcohol

: 449177-94-0,813460-60-5
3-[(2,2,3,3,3-pentafluoropropoxy)methyl]-3-methyloxetane

Guidance literature:: With tetrabutylammomium bromide; potassium hydroxide; In water; at 95 ℃; for 24h; Inert atmosphere;
DOI:10.1016/j.jfluchem.2016.09.001

Reference yield: 40.0%

: 3864-43-5
methanesulfonic acid 3-methyloxetan-3-ylmethyl ester

: 422-05-9
2,2,3,3,3-pentafluoropropyl alcohol

: 449177-94-0,813460-60-5
3-[(2,2,3,3,3-pentafluoropropoxy)methyl]-3-methyloxetane

Guidance literature:: 2,2,3,3,3-pentafluoropropyl alcohol; With sodium hydride; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 2h; Inert atmosphere;

methanesulfonic acid 3-methyloxetan-3-ylmethyl ester; In N,N-dimethyl-formamide; at 0 - 65 ℃; for 40h; Inert atmosphere;
DOI:10.1246/bcsj.20100155

Reference yield:

: 77-85-0
2-(hydroxymethyl)-2-methylpropane-1,3-diol

: 449177-94-0,813460-60-5
3-[(2,2,3,3,3-pentafluoropropoxy)methyl]-3-methyloxetane

Guidance literature:: Multi-step reaction with 3 steps

1: sodium bromide; sulfuric acid / 168 h / 110 °C / Inert atmosphere

2: tetrabutylammomium bromide; sodium hydroxide / dichloromethane / 24 h / Inert atmosphere; Reflux

3: tetrabutylammomium bromide; potassium hydroxide / water / 24 h / 95 °C / Inert atmosphere

With sulfuric acid; tetrabutylammomium bromide; sodium bromide; potassium hydroxide; sodium hydroxide; In dichloromethane; water;
DOI:10.1016/j.jfluchem.2016.09.001