Benzoic acid, 2-[[4-(methoxycarbonyl)phenyl]methyl]-, methyl ester

Base Information

Chemical Name:Benzoic acid, 2-[[4-(methoxycarbonyl)phenyl]methyl]-, methyl ester
CAS No.:89069-02-3
Molecular Formula:C17H16O4
Molecular Weight:284.312
Hs Code.:
DSSTox Substance ID:DTXSID30449807
Nikkaji Number:J802.807I
Wikidata:Q82269325

Synonyms:89069-02-3;Benzoic acid, 2-[[4-(methoxycarbonyl)phenyl]methyl]-, methyl ester;SCHEMBL70372;DTXSID30449807;2,4'-Methylenedibenzoic acid dimethyl ester

Suppliers and Price of Benzoic acid, 2-[[4-(methoxycarbonyl)phenyl]methyl]-, methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Benzoic acid, 2-[[4-(methoxycarbonyl)phenyl]methyl]-, methyl ester

Chemical Property:

XLogP3:2.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:6
Exact Mass:284.10485899
Heavy Atom Count:21
Complexity:358

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1=CC=C(C=C1)CC2=CC=CC=C2C(=O)OC

Technology Process of Benzoic acid, 2-[[4-(methoxycarbonyl)phenyl]methyl]-, methyl ester

There total 4 articles about Benzoic acid, 2-[[4-(methoxycarbonyl)phenyl]methyl]-, methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 141883-39-8
2,4'-(hydroxyimino-methanediyl)-di-benzoic acid dimethyl ester

: 89069-02-3
methyl 2-(4-(methoxycarbonyl)benzyl)benzoate

Guidance literature:: With ammonium formate; palladium on activated charcoal; In methanol; for 4h; Ambient temperature;

Reference yield: 83.0%

: 67-56-1
methanol

: 125587-45-3
methyl 4-[(2-tosylhydrazono)methyl]benzoate

: 6630-33-7
ortho-bromobenzaldehyde

: 89069-02-3
methyl 2-(4-(methoxycarbonyl)benzyl)benzoate

Guidance literature:: With 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate; potassium carbonate; at 100 ℃; for 3h; chemoselective reaction; Schlenk technique; Inert atmosphere;
DOI:10.1021/acs.orglett.0c00579

Reference yield:

: 1571-08-0
methyl 4-formylbenzoate

: 89069-02-3
methyl 2-(4-(methoxycarbonyl)benzyl)benzoate

Guidance literature:: Multi-step reaction with 2 steps

1: methanol / 20 °C / Schlenk technique; Inert atmosphere

2: palladium diacetate; 1,1'-bis-(diphenylphosphino)ferrocene; potassium carbonate / 3 h / 100 °C / Schlenk technique; Inert atmosphere

With 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate; potassium carbonate; In methanol;
DOI:10.1021/acs.orglett.0c00579