[(3,4-Dimethylcyclohex-1-en-1-yl)oxy](trimethyl)silane

Base Information

Chemical Name:[(3,4-Dimethylcyclohex-1-en-1-yl)oxy](trimethyl)silane
CAS No.:89088-84-6
Molecular Formula:C11H22OSi
Molecular Weight:
Hs Code.:
DSSTox Substance ID:DTXSID20542215

Synonyms:89088-84-6;DTXSID20542215;[(3,4-Dimethylcyclohex-1-en-1-yl)oxy](trimethyl)silane

Suppliers and Price of [(3,4-Dimethylcyclohex-1-en-1-yl)oxy](trimethyl)silane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of [(3,4-Dimethylcyclohex-1-en-1-yl)oxy](trimethyl)silane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:2
Exact Mass:198.143991855
Heavy Atom Count:13
Complexity:203

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1CCC(=CC1C)O[Si](C)(C)C

Technology Process of [(3,4-Dimethylcyclohex-1-en-1-yl)oxy](trimethyl)silane

There total 2 articles about [(3,4-Dimethylcyclohex-1-en-1-yl)oxy](trimethyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 75-77-4
chloro-trimethyl-silane

: 75337-05-2,79980-78-2,101758-35-4,5515-76-4
4-methyl-2-cyclohexenone

: 917-54-4
methyllithium

: cis-3,4-dimethyl-1-(trimethylsiloxy)cyclohexene

: 89088-84-6
trans-3,4-dimethyl-1-(trimethylsiloxy)cyclohexene

Guidance literature:: With N,N,N,N,N,N-hexamethylphosphoric triamide; copper(I) bromide dimethylsulfide complex; triethylamine; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1021/jo00221a015

Reference yield:

: 75-77-4
chloro-trimethyl-silane

: 75337-05-2
(+)-(R)-4-methyl-2-cyclohexene-1-one

: 89088-84-6
((R)-4,5-Dimethyl-cyclohexa-1,5-dienyloxy)-trimethyl-silane

Guidance literature:: Yield given. Multistep reaction; 1.) Et₂O, 0 deg C;
DOI:10.1021/jo00181a050

Reference yield:

: 89088-84-6
trans-3,4-dimethyl-1-(trimethylsiloxy)cyclohexene

: 97997-16-5
2-(tert-butyldimethylsiloxy)-3β,4α-dimethylcyclohexanone

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) m-chloroperoxybenzoic acid (mCPBA), 2.) triethylammonium fluoride, silica gel / 1.) hexane, a) -15 deg C, 15 min, b) 20 deg C, 1 h, 2.) CH₂Cl₂, 5 h

2: imidazole / dimethylformamide / Ambient temperature

With 1H-imidazole; silica gel; triethylamine hydrofluoride; 3-chloro-benzenecarboperoxoic acid; In N,N-dimethyl-formamide;
DOI:10.1021/jo00221a015