4-tert-Butyl-1-[(methanesulfonyl)methyl]cyclohex-1-ene

Base Information

Chemical Name:4-tert-Butyl-1-[(methanesulfonyl)methyl]cyclohex-1-ene
CAS No.:89278-78-4
Molecular Formula:C12H22O2S
Molecular Weight:230.371
Hs Code.:
DSSTox Substance ID:DTXSID90533014

Synonyms:89278-78-4;4-tert-Butyl-1-[(methanesulfonyl)methyl]cyclohex-1-ene;DTXSID90533014

Suppliers and Price of 4-tert-Butyl-1-[(methanesulfonyl)methyl]cyclohex-1-ene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 4-tert-Butyl-1-[(methanesulfonyl)methyl]cyclohex-1-ene

Chemical Property:

XLogP3:2.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:230.13405111
Heavy Atom Count:15
Complexity:339

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(C)(C)C1CCC(=CC1)CS(=O)(=O)C

Technology Process of 4-tert-Butyl-1-[(methanesulfonyl)methyl]cyclohex-1-ene

There total 5 articles about 4-tert-Butyl-1-[(methanesulfonyl)methyl]cyclohex-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 3.7%

C₈H₉ClO₂S: 89278-87-5
C₈H₉ClO₂S

: 98-53-3
4-tercbutyl-cyclohexanone

: 67-71-0
dimethylsulfone

: 89278-78-4
(4-tert-Butyl-1-cyclohexenyl)methyl methyl sulfone

: 89278-77-3
<1-<(Methylsulfonyl)methyl>-1-(p-chlorophenoxy)-4-tert-butyl>cyclohexane

: 106-48-9,82344-39-6
4-chloro-phenol

Guidance literature:: at -60 ℃; for 3h; Product distribution;
DOI:10.1021/jo00182a016

Reference yield:

: 98-53-3
4-tercbutyl-cyclohexanone

: 89278-78-4
(4-tert-Butyl-1-cyclohexenyl)methyl methyl sulfone

Guidance literature:: Multi-step reaction with 3 steps

1: 85 percent / LDA / tetrahydrofuran / 48 h / 25 °C

2: 89 percent / MCPBA / CH₂Cl₂ / 1 h / -35 - 0 °C

3: tetrabutylammonium fluoride, 4A molecular sieves / tetrahydrofuran / Ambient temperature; 1.) overnight, 2.) 2 h

With 4 A molecular sieve; tetrabutyl ammonium fluoride; 3-chloro-benzenecarboperoxoic acid; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane;

Reference yield:

: 116203-94-2
[2-(4-tert-Butyl-cyclohexylidenemethylsulfanyl)-ethyl]-trimethyl-silane

: 89278-78-4
(4-tert-Butyl-1-cyclohexenyl)methyl methyl sulfone

Guidance literature:: Multi-step reaction with 2 steps

1: 89 percent / MCPBA / CH₂Cl₂ / 1 h / -35 - 0 °C

2: tetrabutylammonium fluoride, 4A molecular sieves / tetrahydrofuran / Ambient temperature; 1.) overnight, 2.) 2 h

With 4 A molecular sieve; tetrabutyl ammonium fluoride; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane;