2-Cyclohexen-1-one, 2-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]-

Base Information

Chemical Name:2-Cyclohexen-1-one, 2-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]-
CAS No.:89439-07-6
Molecular Formula:C13H24O2Si
Molecular Weight:240.418
Hs Code.:
DSSTox Substance ID:DTXSID10459484
Nikkaji Number:J2.044.879B

Synonyms:2-Cyclohexen-1-one, 2-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]-;89439-07-6;DTXSID10459484;2-(tert-Butyldimethylsiloxymethyl)-2-cyclohexene-1-one

Suppliers and Price of 2-Cyclohexen-1-one, 2-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-Cyclohexen-1-one, 2-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:240.154556538
Heavy Atom Count:16
Complexity:298

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(C)(C)[Si](C)(C)OCC1=CCCCC1=O

Technology Process of 2-Cyclohexen-1-one, 2-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]-

There total 2 articles about 2-Cyclohexen-1-one, 2-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 105956-40-9
2-(hydroxymethyl)cyclohex-2-en-1-one

: 18162-48-6
tert-butyldimethylsilyl chloride

: 89439-07-6
2-(tert-butyl-dimethyl-silanyloxymethyl)-cyclohex-2-enone

Guidance literature:: With dmap; triethylamine; In dichloromethane; at 20 ℃; for 2h;
DOI:10.1016/j.bmcl.2012.01.006

Reference yield:

: 930-68-7
cyclohexenone

: 89439-07-6
2-(tert-butyl-dimethyl-silanyloxymethyl)-cyclohex-2-enone

Guidance literature:: Multi-step reaction with 2 steps

1: 1H-imidazole

2: dmap; triethylamine / dichloromethane / 2 h / 20 °C

With 1H-imidazole; dmap; triethylamine; In dichloromethane; 1: Morita-Baylis-Hillman reaction;
DOI:10.1016/j.bmcl.2012.01.006

Reference yield: 98.0%

: 89439-07-6
2-(tert-butyl-dimethyl-silanyloxymethyl)-cyclohex-2-enone

: (S)-2-{[(tert-butyldimethylsilyl)oxy]methyl}cyclohex-2-enol

Guidance literature:: 2-(tert-butyl-dimethyl-silanyloxymethyl)-cyclohex-2-enone; With borane-THF; (3aR)-1-methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole; In tetrahydrofuran; at 0 ℃; for 0.0833333h;

2-(tert-butyl-dimethyl-silanyloxymethyl)-cyclohex-2-enone; In tetrahydrofuran; for 0.166667h;
DOI:10.1055/a-1697-7477