1-(Triphenylmethoxy)but-3-en-2-ol

Base Information

Chemical Name:1-(Triphenylmethoxy)but-3-en-2-ol
CAS No.:89543-83-9
Molecular Formula:C23H22O2
Molecular Weight:330.426
Hs Code.:
DSSTox Substance ID:DTXSID00527823

Synonyms:1-trityloxybut-3-en-2-ol;89543-83-9;1-(Triphenylmethoxy)but-3-en-2-ol;1-(trityloxy)but-3-en-2-ol;SCHEMBL2111430;DTXSID00527823;BXJGLPROAVAGKO-UHFFFAOYSA-N;1-(TRITYLOXY)-3-BUTEN-2-OL

Suppliers and Price of 1-(Triphenylmethoxy)but-3-en-2-ol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of 1-(Triphenylmethoxy)but-3-en-2-ol

Chemical Property:

XLogP3:4.7
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:7
Exact Mass:330.161979940
Heavy Atom Count:25
Complexity:341

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C=CC(COC(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3)O

Technology Process of 1-(Triphenylmethoxy)but-3-en-2-ol

There total 7 articles about 1-(Triphenylmethoxy)but-3-en-2-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 497-06-3,86161-40-2
3,4-butenediol

: 76-83-5
trityl chloride

: 89543-83-9
1-triphenylmethoxy-but-3-en-2-ol

Guidance literature:: With dmap; triethylamine; In tetrahydrofuran; at 0 - 20 ℃; regioselective reaction; Inert atmosphere;
DOI:10.1021/jo201110z

Reference yield: 73.0%

: 213681-85-7
(S)-1-(t-butyldiphenylsiloxy)-2-(1,3-dithian-2-yl)propane

: 2-Methyl-3-trityloxymethyl-oxirane

: 89543-83-9
1-triphenylmethoxy-but-3-en-2-ol

: 3-{2-[(S)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-[1,3]dithian-2-yl}-1-trityloxy-butan-2-ol

Guidance literature:: With n-butyllithium; In tetrahydrofuran; for 3h; Yields of byproduct given; Ambient temperature;
DOI:10.1055/s-1998-1825

Reference yield: 68.0%

: 1449782-41-5
butyl 2-(trityloxy)acetate

: 3536-96-7
vinylmagnesium chloride

: 89543-83-9
1-triphenylmethoxy-but-3-en-2-ol

Guidance literature:: butyl 2-(trityloxy)acetate; With diisobutylaluminium hydride; In dichloromethane; cyclohexane; at -78 ℃; for 0.333333h;

vinylmagnesium chloride; In tetrahydrofuran; dichloromethane; cyclohexane; at -78 - 20 ℃;
DOI:10.1021/ol4020078