1,1-Dichloro-7,7-dimethyl-5-phenyl-4,6-dioxaspiro[2.4]heptane

Base Information

Chemical Name:1,1-Dichloro-7,7-dimethyl-5-phenyl-4,6-dioxaspiro[2.4]heptane
CAS No.:89995-53-9
Molecular Formula:C₁₃H₁₄Cl₂O₂
Molecular Weight:273.159
Hs Code.:
DSSTox Substance ID:DTXSID00527601

Synonyms:89995-53-9;DTXSID00527601;1,1-Dichloro-7,7-dimethyl-5-phenyl-4,6-dioxaspiro[2.4]heptane

Suppliers and Price of 1,1-Dichloro-7,7-dimethyl-5-phenyl-4,6-dioxaspiro[2.4]heptane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of 1,1-Dichloro-7,7-dimethyl-5-phenyl-4,6-dioxaspiro[2.4]heptane

Chemical Property:

XLogP3:3.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:272.0370851
Heavy Atom Count:17
Complexity:323

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(C2(CC2(Cl)Cl)OC(O1)C3=CC=CC=C3)C

Technology Process of 1,1-Dichloro-7,7-dimethyl-5-phenyl-4,6-dioxaspiro[2.4]heptane

There total 4 articles about 1,1-Dichloro-7,7-dimethyl-5-phenyl-4,6-dioxaspiro[2.4]heptane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 67-66-3,8013-54-5
chloroform

: 22940-38-1
4,4-dimethyl-5-methylene-2-phenyl-1,3-dioxolane

: 89995-53-9
1,1-Dichloro-7,7-dimethyl-5-phenyl-4,6-dioxa-spiro[2.4]heptane

Guidance literature:: With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride; Ambient temperature;
DOI:10.1007/BF00842826

Reference yield:

: 1120-79-2
1-bromomethyl-2,2-dimethyloxirane

: 89995-53-9
1,1-Dichloro-7,7-dimethyl-5-phenyl-4,6-dioxa-spiro[2.4]heptane

Guidance literature:: Multi-step reaction with 3 steps

1: 45 percent / BF₃*etherate / Heating

2: 59 percent / natrium diethylene glycolate / 3 h / 60 - 70 °C

3: 75 percent / 50percent aq. NaOH, TEBA / Ambient temperature

With sodium hydroxide; boron trifluoride diethyl etherate; N-benzyl-N,N,N-triethylammonium chloride; diethylene glycol monosodium salt;
DOI:10.1007/BF00842826

Reference yield:

: 89995-41-5
5-Bromomethyl-4,4-dimethyl-2-phenyl-[1,3]dioxolane

: 89995-53-9
1,1-Dichloro-7,7-dimethyl-5-phenyl-4,6-dioxa-spiro[2.4]heptane

Guidance literature:: Multi-step reaction with 2 steps

1: 59 percent / natrium diethylene glycolate / 3 h / 60 - 70 °C

2: 75 percent / 50percent aq. NaOH, TEBA / Ambient temperature

With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride; diethylene glycol monosodium salt;
DOI:10.1007/BF00842826