Methyl 2-cyano-3-phenyloxirane-2-carboxylate

Base Information

Chemical Name:Methyl 2-cyano-3-phenyloxirane-2-carboxylate
CAS No.:90179-18-3
Molecular Formula:C11H9NO3
Molecular Weight:203.197
Hs Code.:
DSSTox Substance ID:DTXSID60551068
Nikkaji Number:J1.180.040H

Synonyms:methyl 2-cyano-3-phenyloxirane-2-carboxylate;90179-18-3;DTXSID60551068;AKOS015905638;methyl 2-cyano-3-phenyl-2-oxiranecarboxylate

Suppliers and Price of Methyl 2-cyano-3-phenyloxirane-2-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Methyl 2-cyano-3-phenyloxirane-2-carboxylate

Chemical Property:

XLogP3:1.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:3
Exact Mass:203.058243149
Heavy Atom Count:15
Complexity:313

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1(C(O1)C2=CC=CC=C2)C#N

Technology Process of Methyl 2-cyano-3-phenyloxirane-2-carboxylate

There total 11 articles about Methyl 2-cyano-3-phenyloxirane-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 14533-86-9
methyl (E)-2-cyano-3-phenylprop-2-enoate

: 60239-39-6,60239-40-9,90179-18-3
rac-(2R,3S)-methyl 2-cyano-3-phenyloxirane-2-carboxylate

Guidance literature:: With hydrotalcite; dihydrogen peroxide; In methanol; at 20 ℃; for 1h;
DOI:10.1016/0040-4039(95)00675-3

Reference yield: 96.0%

: 100-52-7
benzaldehyde

: 105-34-0
methyl 2-cyanoacetate

: 60239-39-6,60239-40-9,90179-18-3
rac-(2R,3S)-methyl 2-cyano-3-phenyloxirane-2-carboxylate

Guidance literature:: With sodium hypochlorite; aluminum oxide; for 1.5h; Ambient temperature;
DOI:10.1055/s-1987-28104

Reference yield: 72.0%

: 14856-79-2
N-benzyl(trimethylsilyl)amine

: 105-34-0
methyl 2-cyanoacetate

: 60239-39-6,60239-40-9,90179-18-3
rac-(2R,3S)-methyl 2-cyano-3-phenyloxirane-2-carboxylate

Guidance literature:: N-benzyl(trimethylsilyl)amine; With oxygen; 5,15,10,20-tetraphenylporphyrin; In tetrahydrofuran; at 20 ℃; for 0.0416667h; Photolysis;

methyl 2-cyanoacetate; In tetrahydrofuran;
DOI:10.1039/c4cc04932b