Phenyl(dipropyl)phosphane

Base Information

• Chemical Name: Phenyl(dipropyl)phosphane
• CAS No.: 7650-83-1
• Molecular Formula: C12H19P
• Molecular Weight: 194.257
• European Community (EC) Number: 653-791-5
• NSC Number: 158473
• DSSTox Substance ID: DTXSID30303475
• Nikkaji Number: J1.012.812I
• Wikidata: Q82048796
• Mol file: 7650-83-1.mol

Synonyms:phenyl(dipropyl)phosphane;7650-83-1;(Dipropyl)-phenylphosphine;DI-n-PROPYLPHENYLPHOSPHINE;phenyldipropylphosphine;NSC158473;phenyl(dipropyl)phosphine;SCHEMBL301087;DTXSID30303475;AKOS024323757;NSC-158473

Chemical Property of Phenyl(dipropyl)phosphane

Chemical Property:

• Vapor Pressure: 0.0109mmHg at 25°C
• Boiling Point: 271.1°Cat760mmHg
• Flash Point: 122°C
• PSA: 13.59000
• Density: g/cm³
• LogP: 3.61380
• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 5
• Exact Mass: 194.122437604
• Heavy Atom Count: 13
• Complexity: 110

Purity/Quality:

98%,99%, ^*data from raw suppliers

(DIPROPYL)-PHENYLPHOSPHINE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CCCP(CCC)C1=CC=CC=C1

Technology Process of Phenyl(dipropyl)phosphane

There total 4 articles about Phenyl(dipropyl)phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

di-n-propylphenylphosphine oxide (66232-91-5) → (dipropyl)(phenyl)phosphine (7650-83-1)

Guidance literature:

With polymethylhydrosiloxane; In neat (no solvent); at 175 ℃; for 4h; Reagent/catalyst; Temperature; Time; Inert atmosphere; Microwave irradiation; Green chemistry;

DOI:10.1002/hc.21376

Reference yield: 63.0%

propyl bromide (106-94-5) + Dichlorophenylphosphine (644-97-3) → (dipropyl)(phenyl)phosphine (7650-83-1)

Guidance literature:

With magnesium; In diethyl ether; at 20 ℃; Inert atmosphere;

DOI:10.1039/c2gc35503e

Reference yield:

n-propylmagnesium bromide (927-77-5) + Dichlorophenylphosphine (644-97-3) → (dipropyl)(phenyl)phosphine (7650-83-1)

Guidance literature:

With diethyl ether;

upstream raw materials:

n-propylmagnesium bromide

Dichlorophenylphosphine

propyl bromide

di-n-propylphenylphosphine oxide

Downstream raw materials:

methyl-phenyl-dipropyl-phosphonium; iodide

Dipropyl-phenyl-<2,7-dibrom-fluorenyliden-(9)>-phosphoran

Phenyl-di-n-propyl-phosphintellurid

trans-{RuCl₂(CO)2(C₁₂H₁₉P)2}