(Z)-Cycloundecene

Base Information

• Chemical Name: (Z)-Cycloundecene
• CAS No.: 13151-61-6
• Molecular Formula: C₁₁H₂₀
• Molecular Weight: 152.28
• Hs Code.: 2902199090
• DSSTox Substance ID: DTXSID001016351
• Nikkaji Number: J401.907E,J615.494H
• Mol file: 13151-61-6.mol

Synonyms:cycloundecene;(Z)-Cycloundecene;Cycloundecene(Z);13151-61-6;c-Cycloundecene;1-Cycloundecene;cis-cycloundecene;Cycloundecene (Z);(10Z)-cycloundecene;(Z)-1-Cycloundecene;GMUVJAZTJOCSND-UPHRSURJSA-N;DTXSID001016351

Chemical Property of (Z)-Cycloundecene

Chemical Property:

• Vapor Pressure: 0.207mmHg at 25°C
• Boiling Point: 216.3°C at 760 mmHg
• Flash Point: 76.1°C
• PSA: 0.00000
• Density: 0.808g/cm³
• LogP: 4.06710
• XLogP3: 5.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 152.156500638
• Heavy Atom Count: 11
• Complexity: 90.6

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCCCC=CCCCC1
• Isomeric SMILES: C1CCCC/C=C\CCCC1

Technology Process of (Z)-Cycloundecene

There total 7 articles about (Z)-Cycloundecene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

12,12-dimorpholino-cis-bicyclo<9.1.0>dodecane (79985-05-0,80009-84-3) → cis-Cycloundecen (13151-61-6) + 5-morpholino-2,3,6,7-tetrahydro-1,4-oxazepine (113628-18-5)

Guidance literature:

at 650 ℃; under 1E-05 - 0.0001 Torr;

DOI:10.1021/jo00243a040

Reference yield:

Isobutyric acid cycloundecyl ester (109701-92-0) → cycloundecanol (24469-57-6) + cis-Cycloundecen (13151-61-6) + trans-cycloundecane (13151-60-5)

Guidance literature:

With hydrogenchloride; bromomagnesium diisopropylamide; methyl iodide; Yield given. Multistep reaction. Yields of byproduct given; 1) -40 deg C, Et₂O, 2 h; 2) benzene, reflux, 2 h; RT, 15 min;

DOI:10.1016/S0040-4020(01)88162-X

Reference yield:

Cycloundecyl-phenylacetat (42463-70-7) → cis-Cycloundecen (13151-61-6)

Guidance literature:

With (photolysis); In hexane; Quantum yield; Irradiation;

DOI:10.1021/ja00797a022

upstream raw materials:

cycloundecyne

trans-cycloundecane

toluene-4-sulfonic acid

acetic acid

Downstream raw materials:

trans-cycloundecane

Refernces

• 1、 Aubert, Corinne,Begue, Jean-Pierre,Biellmann, Jean-Francois. "β'β ANIONIC ELIMINATION OF CARBOXYLIC ESTERS". . p. 5581 - 5590. Retrieved 2007/10/02.