Bis(beta-carbomethoxyethyl)tin dichloride

Base Information

• Chemical Name: Bis(beta-carbomethoxyethyl)tin dichloride
• CAS No.: 10175-01-6
• Molecular Formula: C8H14 Cl2 O4 Sn
• Molecular Weight: 363.813
• DSSTox Substance ID: DTXSID201210545
• Mol file: 10175-01-6.mol

Synonyms:10175-01-6;Bis(carbomethoxyethyl)dichlorotin;methyl 3-[dichloro-(3-methoxy-3-oxopropyl)stannyl]propanoate;Bis(beta-carbomethoxyethyl)tin dichloride;Dimethyl 3,3'-(dichlorostannylene)dipropionate;3,3/'(DICHLOROSTANNYLENE)BIS(METHYLPROPANOATE);Propionic acid, 3,3'-(dichlorostannylene)di-, dimethyl ester;Propanoic acid, 3,3'-(dichlorostannylene)bis-, 1,1'-dimethyl ester;dimethyl 3,3'-(dichlorostannanediyl)dipropanoate;3,3(DICHLOROSTANNYLENE)BIS(METHYLPROPANOATE);SCHEMBL4321946;DTXSID201210545;MFCD00271043;AKOS024390569;LS-124627;1,1'-Dimethyl 3,3'-(dichlorostannylene)bis[propanoate]

Chemical Property of Bis(beta-carbomethoxyethyl)tin dichloride

Chemical Property:

• Melting Point: 132°C
• Boiling Point: 338.1°Cat760mmHg
• Flash Point: 158.3°C
• PSA: 52.60000
• Density: g/cm³
• LogP: 2.03240
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 8
• Exact Mass: 363.929117
• Heavy Atom Count: 15
• Complexity: 211

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC(=O)CC[Sn](CCC(=O)OC)(Cl)Cl

Technology Process of Bis(beta-carbomethoxyethyl)tin dichloride

There total 5 articles about Bis(beta-carbomethoxyethyl)tin dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

tin (7440-31-5) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) → (CH3CO2CH2CH2)2SnCl2 (10175-01-6)

Guidance literature:

With hydrogenchloride; with HCl gas;

Reference yield:

tin (7440-31-5) + 2-methoxycarbonylethyltin trichloride (59586-13-9) → bis(2-methoxycarbonylethyl)tin dichloride (10175-01-6) + ClSn(CH2CH2CO2CH3)3 (68983-12-0)

Guidance literature:

In 1,2-dimethoxyethane; refluxing for 10 h under N2; detd. by NMR spectrum;

DOI:10.1016/S0022-328X(00)99501-9

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + tin (7440-31-5) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) → 2-methoxycarbonylethyltin trichloride (59586-13-9) + bis(2-methoxycarbonylethyl)tin dichloride (10175-01-6)

Guidance literature:

In diethyl ether; reaction of tin, CH3OCOCH=CH2 and dry HCl in ethyl ether, product mixt extd. by warm CHCl3; purifn. of monoester by fractional recrystn.;

DOI:10.1016/0022-328X(83)85115-8

upstream raw materials:

tin

2-methoxycarbonylethyltin trichloride

hydrogenchloride

acrylic acid methyl ester

Downstream raw materials:

Cl₂Sn(CH₂CH₂COOCH₂CH₂CH₂CH₃)2

Refernces

• 1、 Burley, Joseph W.,Hutton, Ronald E.,Jolley, Michael R.J.,Groenenboom, Cornelis J.. "β-SUBSTITUTED ALKYLTIN HALIDES. III. SYNTHESIS OF TRIALKYLTIN HALIDES AND TETRAALKYLTINS". . p. 189 - 202. Retrieved 2007/10/02.