Cyclohex-1-ene-1-carboxylic anhydride

Base Information

Chemical Name:Cyclohex-1-ene-1-carboxylic anhydride
CAS No.:917906-15-1
Molecular Formula:C14H18O3
Molecular Weight:234.295
Hs Code.:
DSSTox Substance ID:DTXSID50705750
Wikidata:Q82638760

Synonyms:Cyclohex-1-ene-1-carboxylic anhydride;917906-15-1;SCHEMBL8429199;DTXSID50705750

Suppliers and Price of Cyclohex-1-ene-1-carboxylic anhydride

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Cyclohex-1-ene-1-carboxylic anhydride

Chemical Property:

XLogP3:3.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:234.125594432
Heavy Atom Count:17
Complexity:341

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CCC(=CC1)C(=O)OC(=O)C2=CCCCC2

Technology Process of Cyclohex-1-ene-1-carboxylic anhydride

There total 3 articles about Cyclohex-1-ene-1-carboxylic anhydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 636-82-8
cyclohexene-1-carboxylic acid

: 917906-15-1
cyclohex-1-ene-1-carboxylic anhydride

Guidance literature:: With bis(trichloromethyl) carbonate; triethylamine; In ethyl acetate; at 20 ℃; for 0.5h;
DOI:10.1002/anie.200602377

Reference yield:

: 201230-82-2
carbon monoxide

: 28075-50-5
cyclohex-1-en-1-yl trifluoromethane sulfonate

: 917906-15-1
cyclohex-1-ene-1-carboxylic anhydride

: 1192-88-7
1-cyclohexene-1-carboxaldehyde

Guidance literature:: With pyridine; hydrogen; palladium diacetate; catacxium A; In N,N-dimethyl-formamide; at 80 ℃; for 16h; under 15001.5 Torr;
DOI:10.1002/anie.200800994

Reference yield:

: 108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

: 917906-15-1
cyclohex-1-ene-1-carboxylic anhydride

: 1192-88-7
1-cyclohexene-1-carboxaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: lithium hexamethyldisilazane / tetrahydrofuran / -78 - 20 °C / Inert atmosphere

2: palladium diacetate; N,N,N,N,-tetramethylethylenediamine; hydrogen; 1,1'-bis-(diphenylphosphino)ferrocene / toluene / 16 h / 60 °C / 3750.38 Torr / Autoclave

With 1,1'-bis-(diphenylphosphino)ferrocene; N,N,N,N,-tetramethylethylenediamine; hydrogen; palladium diacetate; lithium hexamethyldisilazane; In tetrahydrofuran; toluene;
DOI:10.1021/acs.orglett.9b00765